ISSN:
1600-5759
Source:
Crystallography Journals Online : IUCR Backfile Archive 1948-2001
Topics:
Chemistry and Pharmacology
,
Geosciences
,
Physics
Notes:
The title compound, N,N′-difluoro-N,N′-ethylenedi-p-toluenesulfonamide, C16H18F2N2O4S2·CHCl3, is a novel stable compound of the N—F class of reagents containing two R2N—F functionalities. The compound, as the chloroform solvate, is the first such bis(N—F) compound to be structurally characterized. It adopts a solid-state structure in which the two aromatic rings are antiperiplanar and a combination of weak C—H...F and C—H...O hydrogen bonds [distances and angles range from 3.265 (4) to 3.439 (4) Å and 150 to 170°, respectively] and π-stacking between the rings of different molecules (separations of 3.717 and 3.926 Å) results in a solid-state structure containing well defined channels in which CHCl3 solvent molecules are located. The N—F distances are 1.428 (3) and 1.433 (3) Å.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1107/S0108270101007983
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