ISSN:
1572-8927
Keywords:
nonaqueous solvents
;
amides
;
acetonitrile
;
γ-butyrolactone
;
propylene carbonate
;
conductivities
;
concentrated solutions
;
conductivity maxima
;
chemical hardness
Source:
Springer Online Journal Archives 1860-2000
Topics:
Chemistry and Pharmacology
Notes:
Abstract For nonaqueous electrolytes, using the HSAB principle, we tried to correlate the conductivity maxima κMAX, vs. only two intrinsic parameters: chemical hardness η of the solvent and that of the salt. Thus, not only the nature of the solvent but also that of the salt were taken into account. We were able to predict for a given solvent the variation of κMAX as a function of the hardness of the salt and that of the solvent: κMAX = K(1 − |Δη|/ηSOLVENT) with |Δη| = |ηSOLVENT − ηSALT| and K a constant in S-cm−1 independent of the salt, but not of the solvent.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1023/A:1021758315096
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