ALBERT

Description: With an area exceeding 25 000 km 2 and volumes c. 5000 km 3 , south Peru hosts the Andes’ second largest Neogene ignimbrite field. We document the extent, stratigraphy and chronology of 12 ignimbrite sheets in the Río Ocoña–Cotahuasi–Marán and Colca deep canyons. Based on 74 40 Ar/ 39 Ar and U/Pb age determinations, ignimbrite-forming episodes span 25 myr. Prior to 9 Ma, eight large-volume ignimbrites were produced every 2.4 myr. After 9 Ma, average lulls between small- to moderate-volume ignimbrites decreased to 0.85 myr. The refined volcanic stratigraphy reveals three main features. (1) Larger volume ignimbrites were emplaced by punctuated flare-ups between 25 and 9 Ma during uplift of the Western Cordillera. (2) Numerous smaller ignimbrites were emplaced after 9 Ma as the ignimbrite production rate decreased threefold. This decrease may be due to the declining crustal melting rate, decreasing plate convergence rate after 9 Ma, or more magma stagnation in the shallow crust, which promoted the growth of composite cones. (3) Growth of two volcanic arcs has added twice as much volume ( c. 53 km 3  Ma –1 ) to the Río Ocoña–Cotahuasi–Marán volcanic field than the ignimbrites after 2.27 Ma. Estimated linear arc magma output has, however, decreased twofold (0.15 – 0.08 km 3  km –1  Ma –1 ) from the Early Quaternary to the Pleistocene–Holocene. Supplementary materials: Supplementary text, tables 1–3 and figures 1–4 are available at http://doi.org/10.6084/m9.figshare.c.3147100 .

Description: New structural, U–Th/Pb and Ar/Ar data along the Nyalam section constrain the timing of partial melting, crystallization and deformation in the Greater Himalayan Sequence. Prograde metamorphism was followed by the onset of partial melting at c. 30 Ma. In the central Greater Himalayan Sequence, in situ melts crystallized between 24 and 18 Ma. Subsequent cooling was very fast ( c. 200 °C Ma –1 ) and coeval with the emplacement of undeformed dykes that lasted until c. 15 Ma. In the upper Greater Himalayan Sequence, fast cooling continued until c. 13 Ma. Combined with published P – T and thermochronological data from the Langtang and Dudh Kosi valleys, these data imply that: (a) the partial melt zone thinned over time; (b) the end of melting preceded the end of motion on the Main Central Thrust and the South Tibetan Detachment by 6 and 2 Ma, respectively; (c) the South Tibetan Detachment possibly initiated at c. 25 Ma, probably reactivating a pre-existing thrust; and (d) the present-day topography has been established for 〈6 Ma and focused erosion on the present-day southern slopes of the Himalaya was not active at the time of the exhumation of the Greater Himalayan Sequence. These observations suggest that the Main Central Thrust/South Tibetan Detachment systems are not passive structures induced by focused erosion, as has been suggested previously by some lower crustal channel flow models. Supplementary material: U/Pb, geochemistry and Ar/Ar data, the Ar/Ar analytical procedure, field pictures, T11N26, T11N27, T11N31, T11N53A and T11N40 quartz 〈C〉 axis CPOs are available at http://www.geolsoc.org.uk/SUP18835

Description: Most known primary Au deposits are produced by hydrothermal processes. In this paper, we report Au mineralization of magmatic origin in the Bilihe deposit, China (8.5 Mt averaging 2.9 g/t Au). At Bilihe, most (〉70%) native Au (no detectable Ag) grains are euhedral or subspherical in shape, and occur as trails in dendritic quartz phenocrysts and comb-layered quartz in a moderately reduced, highly fractionated diorite-granite intrusion. The hosting quartz typically has a dendritic core (Q1) and a rim (Q2), with Q1 having concentric zoning and sector zoning in cathodoluminescence (CL) images. Cathodoluminescence petrography and crystallographic modeling reveal that most of the Au trails occur along intersecting crystallographic planes of the host quartz, indicating simultaneous precipitation of both Au and quartz. Abundant melt inclusions are present in Q2 with 〉950°C homogenization temperatures. Minor Au grains also occur in melt inclusions in quartz. In rare cases, necking of Au melt inclusions is present. Neither Q1 nor Q2 contain primary fluid inclusions; only secondary fluid inclusions were found in healed cracks. The above observations indicate a direct magmatic (quartz phenocryst phase) origin for the Au. This defines a new type of Au deposit, and thereby opens new potential for Au exploration. The magmatic origin of Au at Bilihe also implies that enrichment of Au may occur in a source melt prior to volatile escape, which would enhance the possibility of forming a magmatic-hydrothermal Au deposit.

Description: The Yacouba layered complex intrudes the Archean (3.5–2.7 Ga) Kenema-Man craton in the Samapleu-Yorodougou area, western Ivory Coast. In Samapleu area, the complex was recognized in drill holes at three locations: Samapleu Main (SM); Samapleu Extension 1 (E1) and Yorodougou (Yo). It comprises websterites, peridotites and gabbro-norites arranged symmetrically with mafic layers at the center and ultramafic layers at both margins. The complex is inclined at 70–80° to the SE. The thickness of individual layers varies from 2 to 60 m and the total thickness is 120 to 200 m. At the E1 site, the complex extends to depths 〉 500 m. Contacts with the country rock gneiss are characterized by a hybrid zone that is a few meters thick and composed of plagioclase-orthopyroxene bearing metabasites, and locally (E1 site) a metamorphic assemblage of sapphirine-cordierite-sillimanite-spinel ± rutile. This assemblage is attributed to contact metamorphism during intrusion of the complex in the lower crust at a depth of about 25 km. Zircons in country rock gneisses and granulites, as well as in the hybrid facies, yield Archean ages of ~ 2.78 Ga, similar to ages reported in the Man craton. Rutiles in the hybrid zone give a U-Pb age of 2.09 Ga, which is interpreted as the age of contact metamorphism and emplacement of the intrusion. The Samapleu Main and Samapleu Extension 1 sites contain Ni and Cu sulfide deposit with reserves estimated as more than 40 million tons grading 0.25% Ni and 0.22% Cu (Sama Nickel-CI, August 2013). The Ni-Cu mineralization is composed of pentlandite, chalcopyrite, pyrrhotite and rare pyrite, which is disseminated mainly in pyroxenite or occurs as subvertical and semi-massive to massive sulfide veins. The sulfide textures range from matrix ore, net-textured, droplets or breccia textures. Zones enriched in PGM, particularly Pd, are associated with the sulfides and several chromite bands are also present. These observations suggest that an immiscible sulfide liquid formed from a parental silicate liquid and percolated through the crystal pile. The parental melt composition, determined using the Chai and Naldrett [1992] method, has a SiO 2 -rich mafic composition with 53% SiO 2 and 10% MgO. This result, the presence of the hybrid zone, and the trace-element signature determined using the Bedard [1994] method, suggest a mantle-derived basaltic parental magma that had assimilated abundant continental crust. These observations indicate that Samapleu intrusion corresponds to a magmatic conduit of the Yacouba complex as at Jinchuan (China), Voisey’s bay (Canada), Kabanga (Tanzania) or Nkomati (South Africa).

Description: Plutonic bodies of the Central and Southern Vosges Mts can be assigned to two major early Carboniferous magmatic events: a Visean Mg–K event ( c. 345 and 340–336 Ma) and a younger S-type event (329–322 Ma). New petrological, geochemical and Sr–Nd isotopic data highlight the existence of two groups of Mg–K intrusions that might be related to the nature of their primary magma sources; that is, CHUR-like and enriched mantle, which interacted with juvenile and mature crustal material, respectively. The differences between these two groups are explained by a geodynamic scenario involving deep subduction and relamination of the Saxothuringian continental crust under the Moldanubian continent. The relaminated radiogenic Saxothuringian material is thought to have been responsible for dehydration melting of both subducted crust and underlying metasomatized mantle, thereby generating the Mg–K magma subsequently emplaced at middle crustal depth. During their ascent, the mafic magmas interacted with crustally derived felsic melts. Significantly later ( c . 10–15 myr) a widespread mid-crustal anatexis occurred, generating voluminous granite intrusions from mixed crustal sources (paragneisses and/or immature felsic–intermediate metaigneous rocks mixed with Mg–K plutons). The principal heat source for such a major melting event is related to the presence of Mg–K plutons rich in heat-producing elements, which were responsible, after the time lag specified, for a temperature increase at mid-crustal levels by in situ radiogenic heat production. The current study underlines the importance of deep continental crust subduction and relamination for the magmatism and development of collisional orogens. Supplementary material: Analytical methods and data, and supplementary figures, are available at http://www.geolsoc.org.uk/SUP18795 .

Description: A correlation between allochthonous units exposed in the NW Iberian Massif and the southern Armorican Massif is carried out based on lithological associations, structural position, age and geochemistry of protoliths and tectonometamorphic evolution. The units on both sides of the Bay of Biscay are grouped into Upper, Middle and Lower allochthons, whereas an underlying allochthonous thrust sheet identified in both massifs is referred to as the Parautochthon. The Lower Allochthon represents a fragment of the outermost edge of Gondwana that underwent continental subduction shortly after the closure of a Palaeozoic ocean which, in turn, is represented by the Middle Allochthon. The latter consists of supra-subduction ophiolites and metasedimentary sequences alternating with basic, mid-ocean ridge basalt (MORB)-type volcanics, with inheritances suggesting the proximity of a continental domain. Seafloor spreading began at the Cambro-Ordovician boundary and oceanic crust was still formed during the Late Devonian, covering the lifetime of the Rheic Ocean, which is possibly represented by the Middle Allochthon. The opening of the oceanic domain was related to pulling apart the peri-Gondwanan continental magmatic arc, which is represented by the Upper Allochthon.

Description: Tsavorite is exclusively hosted in the Neoproterozoic Metamorphic Mozambique Belt (NMMB). The gemstone mines, widespread between Kalalani (Tanzania) and Mgama Ridge (Kenya), define a continuous corridor over a hundred kilometers in length. The tsavorite is hosted by a metasedimentary sequence defined as the Kurase tsavorite-bearing metasediments (Kurase-TB metasediments) that also hosts rubies. These metasediments underwent amphibolite-facies metamorphism and are surrounded by granulitic gneisses that are also of sedimentary origin (the Kurase high-temperature gneisses). All these rocks lie below the Kasigau Group, a unit dominated by granulite-facies metamagmatic rocks. To constrain the timing of events that led to this peculiar occurrence of tsavorite, we have performed geochronological analyses of thin sections and of separated grains of zircon, monazite, and rutile using LA-ICP-MS and ID-TIMS, as well as 40 Ar/ 39 Ar of muscovite and phlogopite from various lithologies. The results show that the different terranes were metamorphosed synchronously between 620–580 Ma but under different P-T strain conditions. The Kurase-H T gneisses and the rocks from the Kasigau Group are highly strained and underwent granulite-facies metamorphism with abundant partial melting and emplacement of felsic melts between 620 and 600 Ma. Textural observations also underlined a late regional water flux controlling the occurrence of V-free muscovite and monazite mineralizations at 585 Ma. The latter event can be related to the activity of the Galana shear zone, in the east. The Kurase-TB metasediments escaped strain and partial melting. They record amphibolite-facies conditions with static heating, since initial sedimentary structures were locally preserved. The age of the tsavorite mineralization was inferred at 600 Ma from metamorphic zircon rims and monazite from the closest host-rocks, sampled in the mines. Hence, tsavorite crystallization occurred statically at the end of the metamorphic event, probably when the temperature and the amount of volatiles were at maximum levels. Conversely, the ruby formed by local metasomatism of felsic dikes and isolated ultramafic bodies. The rubies are older and zircons and monazites from a ruby-bearing felsic dike (plumasite) were dated at 615 Ma. Finally, data from rutile and micas indicate a global cooling below 430 °C of the whole region between 510 and 500 Ma.