ISSN:
0021-8995
Keywords:
Chemistry
;
Polymer and Materials Science
Source:
Wiley InterScience Backfile Collection 1832-2000
Topics:
Chemistry and Pharmacology
,
Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
,
Physics
Notes:
A study has been made of the effect of solvent nature, concentrations of monomer, initiator and homopolymerization inhibitors, and initial polymer structure on the modification of poly(ethylene terephthalate) (PET) films and fibers by grafting the acrylic acid (AA). AA grafting initiated by radicals formed from thermal decomposition of benzoyl peroxide. It has been established that preswelling of PET in dichloroethane leads to changes in its sorption-diffusion properties and favors an increase in the degree of grafting. Addition of the Fe(II), Ni(II), and Cu(II) salts to AA solution decreased homopolymer yield. The studied process of grafting can be described by equations of diffusion kinetics. Distribution of the poly(acrylic acid) (PAA) over the cross section of samples and a number of physical and chemical properties depend also on conditions of performing the graft polymerization.
Additional Material:
6 Ill.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1002/app.1990.070390412
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