ISSN:
1434-1948
Keywords:
Rhenium
;
Clusters
;
Solid-state structures
;
Chemistry
;
General Chemistry
Source:
Wiley InterScience Backfile Collection 1832-2000
Topics:
Chemistry and Pharmacology
Notes:
The first two Re4 chalcogenide halide clusters (Pr4N)2Re4Q4(CH3CONH)2Cl8 (Q = S, Se) with ionic molecular structures have been synthesized by treatment of neutral molecular clusters Re4Q4Cl8(TeCl2)4 (Q = S, Se) with Pr4NCl in refluxing CH3CN. During the reaction acetonitrile solvent molecules are converted into acetamido ligands, coordinated as dinucleating ligands to Re-Re bonds.
Additional Material:
1 Ill.
Type of Medium:
Electronic Resource
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