ISSN:
1089-7690
Source:
AIP Digital Archive
Topics:
Physics
,
Chemistry and Pharmacology
Notes:
A comprehensive photophysical characterization of a new class of naphthalene derivatives of the important α-oligothiophenes (αn's) has been undertaken in solution at room (293 K) and low (77 K) temperature. This includes absorption and fluorescence spectra, fluorescence quantum yields (φF), and lifetimes (τF), as a function of temperature and solvent. Triplet–triplet absorption spectra and triplet formation quantum yields (φT) were also determined. From the above, all the rate constants for the radiative (kF) and radiationless (kIC and kISC) have been calculated. It is shown that the lowest singlet excited state is an allowed π,π* state in all solvents. The results show that although the behavior of the oligomers is similar to their parent compounds (αn's), significant differences are observed. By comparison of the extinction coefficients of the naph(αn's) and the (αn's), a good correlation was found between naph(αn) and α(n+1). On the basis of this proposed pairing, a consistent blue-shift was observed in the absorption maxima between the compounds here considered and the reference α-oligothiophenes. This indicates that there is some significant twist between the naphthalene and the αn chromophores. The most favorable inter-ring angle between the two chromophores, naphthalene and αn, was predicted on the basis of comparison with theory. © 2001 American Institute of Physics.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1063/1.1397310
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