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  • 1
    Publication Date: 2022-09-27
    Description: Calcareous foraminifer shells (tests) represent one of the most important archives for paleoenvironmental and paleoclimatic reconstruction. To develop a mechanistic understanding of the relationship between environmental parameters and proxy signals, knowledge of the fundamental processes operating during foraminiferal biomineralization is essential. Here, we apply microscopic and diffraction‐based methods to address the crystallographic and hierarchical structure of the test wall of different hyaline foraminifer species. Our results show that the tests are constructed from micrometer‐scale oriented mesocrystals built of nanometer‐scale entities. Based on these observations, we propose a mechanistic extension to the biomineralization model for hyaline foraminifers, centered on the formation and assembly of units of metastable carbonate phases to the final mesocrystal via a non‐classical particle attachment process, possibly facilitated by organic matter. This implies the presence of metastable precursors such as vaterite or amorphous calcium carbonate, along with phase transitions to calcite, which is relevant for the mechanistic understanding of proxy incorporation in the hyaline foraminifers.
    Description: Plain Language Summary: Foraminifers are single celled marine organisms typically half a millimeter in size, which form shells made of calcium carbonate. During their life, the chemical composition of their shells records environmental conditions. By analyzing fossil shells, past conditions can be reconstructed to understand ancient oceans and climate change. To do that correctly, we need to know exactly how foraminifers form their shell. We find that foraminifers build micrometer‐sized mesocrystals which are made of smaller building blocks. This means that the smallest building blocks form first and assemble to form a larger grain, which is oriented in a specific direction. To align all the building blocks, it is possible that they are first unstable and undergo transformation on assembly, during which their composition may change. By understanding and quantifying this process, the composition of the final fossil shell may be understood, ultimately leading to more reliable reconstructions of past environmental change.
    Description: Key Points: Hyaline foraminiferal shells are built of micrometer sized mesocrystalline units. Biomineralization likely includes the formation and assembly of nanoparticles. Nanometer sized units suggest non‐classical crystal growth.
    Description: https://doi.org/10.17617/3.D7HN3I
    Keywords: ddc:561.9 ; ddc:549
    Language: English
    Type: doc-type:article
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  • 2
    Publication Date: 2023-01-21
    Description: Closure of the Central American Seaway (CAS) and hydrology of the Caribbean Sea triggered Northern Hemisphere Glaciation and played an important role in the Pliocene to modern‐day climate re‐establishing the deep and surface ocean currents. New data on Mn/Ca obtained with femtosecond laser ablation inductively coupled plasma mass spectrometry on well‐preserved tests of the epibenthic foraminifer Cibicidoides wuellerstorfi and infaunal C. mundulus contribute to the interpretation of paleoenvironmental conditions of the Caribbean Sea between 5.2 and 2.2 Ma (million years) across the closure of the CAS. Hydrothermal activity at the Lesser Antilles may be a primary source of Mn in the well‐oxygenated Plio‐Pleistocene Caribbean Sea. Incorporation of Mn in the benthic foraminifer shell carbonate is assumed to be affected by surface ocean nutrient cycling, and may hence be an indicator of paleoproductivity.
    Description: Plain Language Summary: The closure of the Panama Isthmus caused the expansion of ice sheets in the Northern Hemisphere and changed the water current dynamics and climate in the Caribbean Sea since the Pliocene (∼5.3 million years ago). New Mn/Ca data measured using femtosecond laser ablation inductively coupled plasma mass spectrometry on the deep‐sea benthic foraminifer species Cibicidoides wuellerstorfi and Cibicidoides mundulus help us understand past environmental conditions of the Caribbean Sea prevailed between 5.2 and 2.2 million years ago. While manganese might be sourced from the surrounding hydrothermal vents, its incorporation in the foraminifer shell carbonate might be related to nutrient cycling and may indicate past biological productivity in the ocean.
    Description: Key Points: Femtosecond‐laser ablation inductively coupled plasma mass spectrometry provides a new approach on distinguishing Mn of the ontogenetic shell calcite from Mn of the authigenic coatings. Ontogenetic Mn within the foraminifer shell calcite may result from the regional nutrient cycle. Mn in the deep eastern Caribbean Sea may mainly derive from hydrothermal sources along the Antilles Island Arc.
    Description: MPIC
    Description: https://doi.org/10.17632/bps7nw7922.1
    Keywords: ddc:560 ; manganese ; Cibicidoides wuellerstorfi ; Cibicidoides mundulus ; Central American Seaway ; trace elements ; hydrothermal ; paleoproductivity
    Language: English
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  • 3
    Publication Date: 2024-02-21
    Description: 〈title xmlns:mml="http://www.w3.org/1998/Math/MathML"〉Abstract〈/title〉〈p xmlns:mml="http://www.w3.org/1998/Math/MathML" xml:lang="en"〉The Mg/Ca of marine calcareous Planktic Foraminifera (PF) shells is commonly used for sea surface temperature reconstructions. However, compared to open marine environments, hypersaline (>40) oligotrophic seas have been shown to accommodate PF with higher Mg/Ca and divergent temperature to Mg/Ca relationships. To investigate influencing factors of PF Mg uptake in hypersaline regions, we measured the Mg/Ca of two flux‐dominating PF species, 〈italic〉Globigerinoides ruber albus〈/italic〉 and 〈italic〉Turborotalita clarkei〈/italic〉, derived from a monthly resolved time series of sediment traps in the Gulf of Aqaba, northern Red Sea as well as the corresponding temperature, salinity, and 〈italic〉p〈/italic〉H values. The PF exhibit elevated Mg/Ca which cannot be explained by post‐deposition or interstitial sediment diagenetic processes. 〈italic〉G. ruber albus〈/italic〉 displays Mg/Ca trends that strongly follow seasonal mixed layer temperature changes. Conversely, 〈italic〉T〈/italic〉. 〈italic〉clarkei〈/italic〉 Mg/Ca trends do not follow temperature but rather show significant Mg/Ca enrichment following mixing of the surface water column. We present a framework for incorporating elevated Mg/Ca into global Mg/Ca‐T calibrations for 〈italic〉G〈/italic〉. 〈italic〉ruber albus〈/italic〉 and present a new Mg/Ca‐T calibration suitable for hypersaline marine environments.〈/p〉
    Description: Plain Language Summary: Past seawater temperature is reconstructed from the magnesium‐to‐calcium ratio (Mg/Ca) in the calcareous shells of a group of marine microplankton called foraminifera. Two foraminifer species, 〈italic〉Globigerinoides ruber albus〈/italic〉 and 〈italic〉Turborotalita clarkei〈/italic〉, are abundant in the Gulf of Aqaba, northern Red Sea, at year‐round high temperatures and salinities. The shells of these foraminifera have elevated Mg/Ca relative to other marine regions, and here, we explore the factors causing this. The Mg/Ca values of both 〈italic〉G〈/italic〉. 〈italic〉ruber albus〈/italic〉 and 〈italic〉T〈/italic〉. 〈italic〉clarkei〈/italic〉 reflect the environmental conditions of the water column. For 〈italic〉G〈/italic〉. 〈italic〉ruber albus〈/italic〉, temperature and salinity appear to be factors responsible for the Mg/Ca trends and elevated values. We incorporate the new Mg/Ca data for 〈italic〉G〈/italic〉. 〈italic〉ruber albus〈/italic〉 to calibrate elevated Mg/Ca with temperature for high‐salinity (>40) marine environments. The Mg/Ca of the deeper dwelling 〈italic〉T〈/italic〉. 〈italic〉clarkei〈/italic〉 show higher ratios following deep mixing of the surface water column and may indicate annually recurring phytoplankton blooms caused by nutrient input into the sunlit ocean surface.〈/p〉
    Description: Key Points: 〈list list-type="bullet"〉 〈list-item〉 〈p xml:lang="en"〉A new Mg/Ca temperature calibration for high salinity environments is presented for 〈italic〉Globigerinoides ruber albus〈/italic〉〈/p〉〈/list-item〉 〈list-item〉 〈p xml:lang="en"〉A framework for incorporating high salinity environments into global Mg/Ca‐T calibrations is provided〈/p〉〈/list-item〉 〈list-item〉 〈p xml:lang="en"〉Enhanced Mg/Ca in subsurface dwelling 〈italic〉Turborotalita clarkei〈/italic〉 may indicate seasonal deep mixing of the upper water column〈/p〉〈/list-item〉 〈/list〉 〈/p〉
    Description: Israel Science Foundation http://dx.doi.org/10.13039/501100003977
    Description: Minerva PhD Fellowship Stipend
    Description: Advance School for Environmental Studies
    Description: https://doi.org/10.1594/PANGAEA.959629
    Description: https://doi.org/10.17617/3.EXFQC2
    Keywords: ddc:551.9 ; Gulf of Aqaba ; Planktic Foraminifera shells ; Mg/Ca ; sea surface temperature reconstructions
    Language: English
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  • 4
    ISSN: 1365-3121
    Source: Blackwell Publishing Journal Backfiles 1879-2005
    Topics: Geosciences
    Notes: The Kostomuksha greenstone belt consists of two lithotectonic terranes, one mafic igneous and the other sedimentary, separated by a major shear zone. The former contains submarine 2.8 Gyr old komatiite-basalt lavas and volcaniclastic lithologies with trace element and isotopic compositions resembling those of recent oceanic flood basalts [ɛNd(T) =+ 2,8, μ.1= 8.73 (Nb/Th)N= 1.5–2.1 (Nb/La)N= 1.0–1.5]. We suggest that the mafic terrane is a remnant of the upper crustal part of an Archaean oceanic plateau derived from partial melting of a mantle plume head. When the plateau reached the continental margin, it collided with the sedimentary terrane but was too buoyant to subduct. As a result, the volcanic section of the plateau was imbricated and obducted thus becoming a new piece of continental crust. The deeper zones were subducted and disappeared from the geological record.
    Type of Medium: Electronic Resource
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  • 5
    ISSN: 1476-4687
    Source: Nature Archives 1869 - 2009
    Topics: Biology , Chemistry and Pharmacology , Medicine , Natural Sciences in General , Physics
    Notes: [Auszug] Hydrous, silica-rich melts migrating through the mantle are preserved as glass inclusions in mantle minerals in xenoliths from Philippine arc lavas. These melts, with chemistries that indicate an origin by very low degrees of melting of the subducted ocean crust, have altered their host ...
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  • 6
    Electronic Resource
    Electronic Resource
    Springer
    Mineralogy and petrology 53 (1995), S. 155-164 
    ISSN: 1438-1168
    Source: Springer Online Journal Archives 1860-2000
    Topics: Geosciences
    Description / Table of Contents: Zusammenfassung Baddeleyit vom Palabora Igneous Complex, Südafrika, gehört zu den reinsten natürlichen Vorkommen von ZrO2. Dies wurde durch Analysen mit verschiedenen Methoden wie Mikrosonde, Neutronenaktivierung, Funken- und Thermionenmassenspektrometrie bestätigt. HfO2 ist mit 1.87 die einzige andere Hauptkomponente, auch die Konzentrationen der anderen HFSE sind relativ hoch im Vergleich zu den anderen Elementen, die nur wenige ppm erreichen. Die REE bilden ein U-förmiges Muster, das als Ausdruck einer stark LREE angereicherten Komponente im Ausgangsgestein gedeutet wird. Das hohe87Sr/86Sr-Initialverhältnis von 0.713085 und das negative ɛNdt von -10.7 belegen, daß diese Komponente über einen langen Zeitraum vor der Bildung des Palabora Igneous Complex angereichert gewesen war. Diese Daten deuten an, daβ der Baddeleyit aus einem Magma kristallisierte, das aus einem angereicherten Mantelreservoir stammte, ähnlich dem, das bei der Bildung der Gruppe 11 Kimberlite beteiligt war.
    Notes: Summary Baddeleyite from Palabora Igneous Complex, South Africa, is among the purest natural ZrO2 phases. This has been demonstrated by using various methods, i.e. microprobe, neutron activation, spark source and thermal ion mass spectrometry. HfO2 with 1.87% is the only other major component. The concentrations of other HFSE are also relatively high, compared to most other elements, that reach only a few ppm. The REE display a U-shaped pattern that is interpreted to be superimposed by a strongly LREE enriched source component. The high87Sr/86Sr initial of 0.713085 and the negative ɛNdt of −10.7 prove that this component was LILE enriched for a long time prior to the formation of the Palabora Igneous Complex. These data indicate that the baddeleyite crystallized from a magma which was derived from an enriched mantle reservoir, similar to that involved in the formation of group II kimberlites.
    Type of Medium: Electronic Resource
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  • 7
    Electronic Resource
    Electronic Resource
    Springer
    International journal of earth sciences 69 (1980), S. 997-1012 
    ISSN: 1437-3262
    Source: Springer Online Journal Archives 1860-2000
    Topics: Geosciences
    Description / Table of Contents: Abstract Spark source mass spectrometry (SSMS) allows the determination of major, minor and trace elements in solid samples. The different techniques for quantitative multielement analyses are described and compared. A precision of about 2% is achieved by peak switching and isotope dilution. The applicability of SSMS in geo- and cosmochemistry is demonstrated by examples.
    Abstract: Résumé La spectrométrie de masse à étincelles (SSMS) permet de déterminer les éléments majeurs, mineurs et les traces dans des échantillons solides. Les différentes techniques pour l'analyse quantitative des éléments sont décrites et comparées. Par balayage séquentiel et dilution isotopique, une précision d'environ 2 % est atteinte. L'application de la «SSMS» en géo- et cosmochimie est démontrée à partir d'exemples.
    Notes: Zusammenfassung Die Funkenmassenspektrometrie (SSMS) ermöglicht die Bestimmung von Haupt-, Neben- und Spurenelementen in Festkörpern. Die verschiedenen Möglichkeiten der quantitativen Multielementanalyse werden beschrieben und verglichen. Mit dem Peaksprungverfahren und der Isotopenverdünnungsmethode erreicht man eine Genauigkeit von ungefähr 2 %. Die Anwendbarkeit der Funkenmassenspektrometrie in der Geo- und Kosmochemie wird an Hand von Beispielen gezeigt.
    Type of Medium: Electronic Resource
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  • 8
    Electronic Resource
    Electronic Resource
    [s.l.] : Nature Publishing Group
    Nature 342 (1989), S. 743-743 
    ISSN: 1476-4687
    Source: Nature Archives 1869 - 2009
    Topics: Biology , Chemistry and Pharmacology , Medicine , Natural Sciences in General , Physics
    Notes: [Auszug] JOCHUM et al reply-Rogers et al. suggest that the continental lithospheric mantle (CLM) may grow at convergent plate margins, although evidence for this process has not been found in spinel Iherzolite xenoliths1. Their comments lead to two important questions in first, how representative are spinel ...
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  • 9
    Electronic Resource
    Electronic Resource
    [s.l.] : Nature Publishing Group
    Nature 306 (1983), S. 431-436 
    ISSN: 1476-4687
    Source: Nature Archives 1869 - 2009
    Topics: Biology , Chemistry and Pharmacology , Medicine , Natural Sciences in General , Physics
    Notes: [Auszug] Analyses on fresh glass samples of mid-ocean ridge basalt yield a uniform ratio K/U = 12,700 ± 200. In contrast, Th/U increases systematically with Th concentration. From these results we calculate an upper limit (1.5 pW kg−1) and a best estimate (0.6 pW ...
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  • 10
    ISSN: 1476-4687
    Source: Nature Archives 1869 - 2009
    Topics: Biology , Chemistry and Pharmacology , Medicine , Natural Sciences in General , Physics
    Notes: [Auszug] Peridotite xenoliths in alkali basalts can be used to obtain direct measurements of element abundances in the continental lithospheric mantle. The abundances of highly incompatible elements in these rocks are difficult to interpret because some of these elements were introduced by alteration ...
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