ISSN:
0030-493X
Keywords:
Chemistry
;
Analytical Chemistry and Spectroscopy
Source:
Wiley InterScience Backfile Collection 1832-2000
Topics:
Chemistry and Pharmacology
Description / Table of Contents:
Some of the observed fragmentation reactions of long-chain aliphatic methoxyesters necessitate the interaction of both functional groups, even when these are located far apart: both alcohol eliminations from the ion formed by α-cleavage to the ether function which contains the ester group are highly specific: they involve a hydrogen atom in the position adjacent to the methoxyl-bearing carbon.
Notes:
Certaines des fragmentations des méthoxyesters aliphatiques à longue chaíne nécessitent l'interation des deux fonctions: les deux éliminations d'alcool que subit l'ion par rupture en α de la fanction éther et comprenant le groupe ester, sont trés spécifiques: elles mettent en cause un atome d'hydrogéne en position adjacente au carbone qui porte le groupe méthoxyle.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1002/oms.1210030315
Permalink
