ISSN:
1572-8862
Keywords:
Metal carbonyls
;
propargylamines
;
models of intermediates
;
metallacyclic compounds
;
organic heterocycles
Source:
Springer Online Journal Archives 1860-2000
Topics:
Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
,
Physics
Notes:
Abstract The reactions of VIII Group metal carbonyls with dipropargylamines and other functionalized alkynes lead to new cluster and binuclear compounds: the ruthenium cluster derivatives may be considered as “models of intermediates” proposed in metal-mediated organic syntheses. The iron and cobalt carbonyls give metallacyclic derivatives which are intermediates in organic syntheses. The structure of Fe3(CO)6(μ-CO)2[(HC ≡ CCMe2)2NH] has been determined by an X-ray diffraction study.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1007/BF01028383
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