ISSN:
1572-901X
Source:
Springer Online Journal Archives 1860-2000
Topics:
Chemistry and Pharmacology
Notes:
Summary Allyl esters react selectively at room temperature with aromatic aldehydes and Nio complexes in alcoholic solvents to form aryl-substituted secondary alcohols. In tetrahydrofuran at 70°, ketones and aliphatic aldehydes react satisfactorily to give tertiary and secondary alcohols respectively. Ligands able to promote oxidative addition exert a favourable influence provided they do not complex to the exclusion of the substrate.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1007/BF01393539
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