ALBERT

Description: Atmospheric emissions of carbon tetrachloride (CCl4) are regulated by the Montreal Protocol due to its role as a strong ozone-depleting substance. The molecule has been the subject of recent increased interest as a consequence of the so-called mystery of CCl4, the discrepancy between atmospheric observations and reported production and consumption. Surface measurements of CCl4 atmospheric concentrations have declined at a rate almost 3 times lower than its lifetime-limited rate, suggesting persistent atmospheric emissions despite the ban. In this paper, we study CCl4 vertical and zonal distributions in the upper troposphere and lower stratosphere (including the photolytic loss region, 70–20 hPa), its trend, and its stratospheric lifetime using measurements from the Michelson Interferometer for Passive Atmospheric Sounding (MIPAS), which operated onboard the ENVISAT satellite from 2002 to 2012. Specifically, we use the MIPAS data product generated with Version 7 of the Level 2 algorithm operated by the European Space Agency.The CCl4 zonal means show features typical of long-lived species of anthropogenic origin that are destroyed primarily in the stratosphere, with larger quantities in the troposphere and a monotonic decrease with increasing altitude in the stratosphere. MIPAS CCl4 measurements have been compared with independent measurements from other satellite and balloon-borne remote sounders, showing a good agreement between the different datasets.CCl4 trends are calculated as a function of both latitude and altitude. Negative trends of about −10 to −15 pptv decade−1 (−10 to −30 % decade−1) are found at all latitudes in the upper troposphere–lower stratosphere region, apart from a region in the southern midlatitudes between 50 and 10 hPa where the trend is positive with values around 5–10 pptv decade−1 (15–20 % decade−1). At the lowest altitudes sounded by MIPAS, we find trends consistent with those determined on the basis of long-term ground-based measurements (−10 to −13 pptv decade−1). For higher altitudes, the trend shows a pronounced asymmetry between the Northern and Southern hemispheres, and the magnitude of the decline rate increases with altitude. We use a simplified model assuming tracer–tracer linear correlations to determine CCl4 lifetime in the lower stratosphere. The calculation provides a global average lifetime of 47 (39–61) years, considering CFC-11 as the reference tracer. This value is consistent with the most recent literature result of 44 (36–58) years.

Description: With the launch of the Sentinel-5 Precursor (S-5P, lifted-off on 13 October 2017), Sentinel-4 (S-4) and Sentinel-5 (S-5)(from 2021 and 2023 onwards, respectively) operational missions of the ESA/EU Copernicus program, a massive amount of atmospheric composition data with unprecedented quality will become available from geostationary (GEO) and low Earth orbit (LEO) observations. Enhanced observational capabilities are expected to foster deeper insight than ever before on key issues relevant for air quality, stratospheric ozone, solar radiation, and climate. A major potential strength of the Sentinel observations lies in the exploitation of complementary information that originates from simultaneous and independent satellite measurements of the same air mass. The core purpose of the AURORA (Advanced Ultraviolet Radiation and Ozone Retrieval for Applications) project is to investigate this exploitation from a novel approach for merging data acquired in different spectral regions from on board the GEO and LEO platforms. A data processing chain is implemented and tested on synthetic observations. A new data algorithm combines the ultraviolet, visible and thermal infrared ozone products into S-4 and S-5(P) fused profiles. These fused products are then ingested into state-of-the-art data assimilation systems to obtain a unique ozone profile in analyses and forecasts mode. A comparative evaluation and validation of fused products assimilation versus the assimilation of the operational products will seek to demonstrate the improvements achieved by the proposed approach. This contribution provides a first general overview of the project, and discusses both the challenges of developing a technological infrastructure for implementing the AURORA concept, and the potential for applications of AURORA derived products, such as tropospheric ozone and UV surface radiation, in sectors such as air quality monitoring and health.

Description: Atmospheric emissions of Carbon tetrachloride CCl4 are regulated by the Montreal Protocol due to its role as a strong ozone-depleting substance. The molecule has been the subject of recent increased interest as a consequence of the so called ``mystery of CCl4,'' the discrepancy between atmospheric observations and reported production and consumption. Surface measurements of CCl4 atmospheric concentrations have declined at a rate almost three times smaller than its lifetime-limited rate, suggesting persistent atmospheric emissions despite the ban. In this paper, we study CCl4 vertical and zonal distributions in the upper troposphere and lower stratosphere (including the photolytic loss region, 70–20 hPa), its trend, and its stratospheric lifetime using measurements from the Michelson Interferometer for Passive Atmospheric Sounding (MIPAS), which operated onboard the ENVISAT satellite from 2002 to 2012. Specifically, we use the MIPAS data product generated with Version 7 of the Level 2 algorithm operated by the European Space Agency. The CCl4 zonal means show features typical of long-lived species of anthropogenic origin that are destroyed primarily in the stratosphere, with larger quantities in the troposphere and a monotonic decrease with increasing altitude in the stratosphere. In the troposphere, the largest concentrations are observed at the latitudes of major industrial countries (20/50°N). The good agreement we find between MIPAS CCl4 and independent measurements from other satellite and balloon-borne remote sounders proves the reliability of the MIPAS dataset. CCl4 trends are calculated as a function of both latitude and altitude. Negative trends are found at all latitudes in the upper-troposphere / lower-stratosphere region, apart from a region in the Southern mid-latitudes between 50 and 10 hPa where the trend is positive. At the lowest altitudes sounded by MIPAS, we find trends consistent with those determined on the basis of long-term ground-based measurements. For higher altitudes, the trend shows a pronounced asymmetry between Northern and Southern Hemispheres, and the magnitude of the decline rate increases with altitude. At 50 hPa the decline is about 30–35 %/decade, close to the lifetime-limited trend. We use a simplified model assuming tracer-tracer linear correlations to determine CCl4 lifetime in the lower stratosphere. The calculation provides a global average lifetime of 46(38–60) years considering CFC-11 as the reference tracer. This value is consistent with the most recent literature result of 44(36–58) years.

Description: The complete data fusion method, generalized to the case of fusing profiles of atmospheric variables retrieved on different vertical grids and referred to different true values, is applied to ozone profiles retrieved from simulated measurements in the ultraviolet, visible, and thermal infrared spectral ranges for the Sentinel-4 and Sentinel-5 missions of the Copernicus program. In this study, the production and characterization of combined low Earth orbit (Sentinel-5) and geostationary Earth orbit (Sentinel-4) fused ozone data is performed. Fused and standard products have been compared and a performance assessment of the generalized complete data fusion is presented. The analysis of the output products of the complete data fusion algorithm and of the standard processing using quality quantifiers demonstrates that the generalized complete data fusion algorithm provides products of better quality when compared with standard products.

Description: The new platforms for Earth observation from space are characterized by measurements made at great spatial and temporal resolutions. While this abundance of information makes it possible to detect and study localized phenomena, it may be difficult to manage this large amount of data for the study of global and large-scale phenomena. A particularly significant example is the use by assimilation systems of Level 2 products that represent gas profiles in the atmosphere. The models on which assimilation systems are based are discretized on spatial grids with horizontal dimensions of the order of tens of kilometres in which tens or hundreds of measurements may fall in the future. A simple procedure to overcome this problem is to extract a subset of the original measurements, but this involves a loss of information. Another option is the use of simple averages of the profiles, but this approach also has some limitations that we will discuss in the paper. A more advanced solution is to resort to the so-called fusion algorithms, capable of compressing the size of the dataset while limiting the information loss. A novel data fusion method, the Complete Data Fusion algorithm, was recently developed to merge a set of retrieved products in a single product a posteriori. In the present paper, we apply the Complete Data Fusion method to ozone profile measurements simulated in the thermal infrared and ultraviolet bands in a realistic scenario. Following this, the fused products are compared with the input profiles; comparisons show that the output products of data fusion have smaller total errors and higher information contents in general. The comparisons of the fused products with the fusing products are presented both at single fusion grid box scale and with a statistical analysis of the results obtained on large sets of fusion grid boxes of the same size. We also evaluate the grid box size impact, showing that the Complete Data Fusion method can be used with different grid box sizes even if this possibility is connected to the natural variability of the considered atmospheric molecule.