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  • 1
    Digitale Medien
    Digitale Medien
    Oxford, UK : Blackwell Science Inc
    Journal of the American Ceramic Society 88 (2005), S. 0 
    ISSN: 1551-2916
    Quelle: Blackwell Publishing Journal Backfiles 1879-2005
    Thema: Maschinenbau , Physik
    Notizen: β-tricalcium phosphate (β-TCP) powder doped with monovalent or divalent metal ions was hot pressed at 1100°C, and the effect of substitutional monovalent and divalent metal ions on mechanical properties of β-TCP was investigated. The sinterability of β-TCP would be enhanced by the substitution of monovalent and divalent metal ions for β-TCP. Sintered β-TCP doped with 7.6 mol% of Mg2+ ion showed a bending strength of 160 MPa. It was found that the substituition of Mg2+ ion up to 9.6 mol% and a small amount of monovalent metal ions for β-TCP is effective to improve the mechanical strength of β-TCP.
    Materialart: Digitale Medien
    Standort Signatur Erwartet Verfügbarkeit
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  • 2
    Digitale Medien
    Digitale Medien
    Westerville, Ohio : American Ceramics Society
    Journal of the American Ceramic Society 86 (2003), S. 0 
    ISSN: 1551-2916
    Quelle: Blackwell Publishing Journal Backfiles 1879-2005
    Thema: Maschinenbau , Physik
    Notizen: A sinter-forging technique was successfully applied to fabricate a silicon nitride with a lutetia (Lu2O3) additive. The sinter-forged specimen had a strongly anisotropic microstructure where rodlike silicon nitride grains preferentially aligned perpendicular to the forging direction. The specimen exhibited superior strength of ∼700 MPa at 1500°C. This strength was highest when compared with previous silicon nitrides at temperatures 〉1400°C. Such superior high-temperature strength was attributed to grain alignment as well as to the refractory grain-boundary glassy phase and the existence of glass-free grain boundaries.
    Materialart: Digitale Medien
    Standort Signatur Erwartet Verfügbarkeit
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  • 3
    Digitale Medien
    Digitale Medien
    Westerville, Ohio : American Ceramics Society
    Journal of the American Ceramic Society 86 (2003), S. 0 
    ISSN: 1551-2916
    Quelle: Blackwell Publishing Journal Backfiles 1879-2005
    Thema: Maschinenbau , Physik
    Notizen: The thermal shock behavior of isotropic and anisotropic porous Si3N4 was evaluated using the water-quenching technique. The critical temperature difference for crack initiation was found to be strongly dependent on the ratio of fracture strength to elastic modulus. Because of a very high strain-to-failure, anisotropic porous Si3N4 showed no macroscopic cracks and was able to retain its strength even at a quenching-temperature difference of ∼1400°C.
    Materialart: Digitale Medien
    Standort Signatur Erwartet Verfügbarkeit
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  • 4
    Digitale Medien
    Digitale Medien
    Westerville, Ohio : American Ceramics Society
    Journal of the American Ceramic Society 84 (2001), S. 0 
    ISSN: 1551-2916
    Quelle: Blackwell Publishing Journal Backfiles 1879-2005
    Thema: Maschinenbau , Physik
    Notizen: A porous CaZrO3/MgO composite with ∼1% nanodispersed platinum was synthesized in air using several in situ reactions, including the pyrolysis of PtO2. The composite had a uniformly open, three-dimensional pore structure (porosity of 56%), with a narrow pore-size distribution. Catalytic NO decomposition to N2 and O2 and NO reduction by C2H4 were investigated up to 900°C. In the absence of oxygen, the NO conversion rate reached ∼52% for the direct decomposition and ∼100% for the reduction by C2H4. The results suggested the possibility of the porous composite as a multifunctional filter for simultaneous filtering of hot gas and removal of NOx.
    Materialart: Digitale Medien
    Standort Signatur Erwartet Verfügbarkeit
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  • 5
    Digitale Medien
    Digitale Medien
    Westerville, Ohio : American Ceramics Society
    Journal of the American Ceramic Society 83 (2000), S. 0 
    ISSN: 1551-2916
    Quelle: Blackwell Publishing Journal Backfiles 1879-2005
    Thema: Maschinenbau , Physik
    Notizen: A ZrB2–SiC composite was prepared from a mixture of zirconium, silicon, and B4C via reactive hot pressing. The three-point bending strength was 506 ± 43 MPa, and the fracture toughness was 4.0 MPa·m1/2. The microstructure of the composite was observed via scanning electron microscopy; the in-situ-formed ZrB2 and SiC were found in agglomerates with a size that was in the particle-size ranges of the zirconium and silicon starting powders, respectively. A model of the microstructure formation mechanism of the composite was proposed, to explain the features of the phase distributions. It is considered that, in the reactive hot-pressing process, the B and C atoms in B4C will diffuse into the Zr and Si sites and form ZrB2 and SiC in situ, respectively. Because the diffusion of Zr and Si atoms is slow, the microstructure (phase distributions) of the obtained composite shows the features of the zirconium and silicon starting powders.
    Materialart: Digitale Medien
    Standort Signatur Erwartet Verfügbarkeit
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  • 6
    Digitale Medien
    Digitale Medien
    Westerville, Ohio : American Ceramics Society
    Journal of the American Ceramic Society 83 (2000), S. 0 
    ISSN: 1551-2916
    Quelle: Blackwell Publishing Journal Backfiles 1879-2005
    Thema: Maschinenbau , Physik
    Notizen: A 3-mol%-Y2O3-doped tetragonal-ZrO2 polycrystal/BaFe12O19 composite was fabricated by powder metallurgical processes, and its mechanical and magnetic properties were evaluated. Post-plastic deformation (i.e., hot-forging) on the composite improved its magnetic properties—that is, saturation magnetization and coercivity—probably because of the alignment of the hexaferrite platelet particles. Post-plastic deformation may represent a new process to complement conventional slurry-pressing under a magnetic field, for obtaining good magnetic properties in a magnetic-particle-dispersed composite.
    Materialart: Digitale Medien
    Standort Signatur Erwartet Verfügbarkeit
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  • 7
    Digitale Medien
    Digitale Medien
    Westerville, Ohio : American Ceramics Society
    Journal of the American Ceramic Society 82 (1999), S. 0 
    ISSN: 1551-2916
    Quelle: Blackwell Publishing Journal Backfiles 1879-2005
    Thema: Maschinenbau , Physik
    Notizen: Composites of BaFe12O19 particles dispersed throughout a 3-mol%-yttria-doped zirconia (3Y-TZP) matrix have been prepared using the pressureless reactive sintering of 3Y-TZP, BaCO3, and γ-Fe2O3 powders. The reaction behavior of the mixed powder was studied with an in situ, high-temperature powder X-ray diffraction technique. The composite that was sintered at 1300°C consisted of submicrometer-sized 3Y-TZP grains and BaFe12O19 particles; the size of the 3Y-TZP grains was ∼100-300 nm, and the size of the BaFe12O19 particles was ∼200-500 nm. Based on the grain size, most of the BaFe12O19 grains presumably had a single-magnetic-domain structure. The 3Y-TZP/20-wt%-BaFe12O19 composite showed high magnetization and coercivity values, despite the low concentration of ferromagnetic phase. Preliminary mechanical tests revealed that the composite possessed moderately good mechanical properties.
    Materialart: Digitale Medien
    Standort Signatur Erwartet Verfügbarkeit
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  • 8
    Digitale Medien
    Digitale Medien
    Westerville, Ohio : American Ceramics Society
    Journal of the American Ceramic Society 82 (1999), S. 0 
    ISSN: 1551-2916
    Quelle: Blackwell Publishing Journal Backfiles 1879-2005
    Thema: Maschinenbau , Physik
    Notizen: The microstructure and mechanical properties of silicon nitride, produced by a superplastic sinter-forging technique, were investigated. The obtained silicon nitride exhibited a highly anisotropic microstructure, where rod-shaped grains tended to be aligned perpendicular to the forging direction. A very high bending strength of 2108 MPa as well as a high fracture toughness of 8.3 MPam1/2 were achieved when a stress was applied perpendicularly to the pressing direction. This very high strength was considered to be due to the reduced flaw size by the superplastic sinter-forging process and the steep R-curve behavior caused by the grain alignment.
    Materialart: Digitale Medien
    Standort Signatur Erwartet Verfügbarkeit
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  • 9
    Digitale Medien
    Digitale Medien
    Westerville, Ohio : American Ceramics Society
    Journal of the American Ceramic Society 81 (1998), S. 0 
    ISSN: 1551-2916
    Quelle: Blackwell Publishing Journal Backfiles 1879-2005
    Thema: Maschinenbau , Physik
    Notizen: Mechanical properties of silicon nitride which was superplastically deformed in plane-strain compression were investigated. Superplastically deformed silicon nitride exhibited a highly anisotropic microstructure, where rod-shaped grains tended to be aligned along the extruding direction. The bending strength and fracture toughness were increased substantially by the deformation process when a stress was applied in the extruding direction. It appears that these improvements were mainly due to effective operation of grain bridging and pull-out by the grain alignment.
    Materialart: Digitale Medien
    Standort Signatur Erwartet Verfügbarkeit
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  • 10
    Digitale Medien
    Digitale Medien
    Oxford, UK : Blackwell Science Inc
    Journal of the American Ceramic Society 88 (2005), S. 0 
    ISSN: 1551-2916
    Quelle: Blackwell Publishing Journal Backfiles 1879-2005
    Thema: Maschinenbau , Physik
    Notizen: The fracture energies of the tape-cast silicon nitride with and without 3 wt% rod-like β-Si3N4 seed addition were investigated by a chevron-notched-beam technique. The material was doped with Lu2O3–SiO2 as sintering additives for giving rigid grain boundaries and good heat resistance. The seeded and tape-cast silicon nitride has anisotropic microstructure, where the fibrous grains grown from seeds were preferentially aligned parallel to the casting direction. When a stress was applied parallel to the fibrous grain alignment direction, the strength measured at 1500°C was 738 MPa, which was almost the same as room temperature strength 739 MPa. The fracture energy of the tape-cast Si3N4 without seed addition was 109 and 454 J/m2 at room temperature and 1500°C, respectively. On the contrary, the fracture energy of the seeded and tape-cast Si3N4 was 301 and 781 J/m2 at room temperature and 1500°C, respectively, when a stress was applied parallel to the fibrous gain alignment. The large fracture energies were attributable primarily to the unidirectional alignment fibrous Si3N4 grains.
    Materialart: Digitale Medien
    Standort Signatur Erwartet Verfügbarkeit
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