ISSN:
1572-8757
Schlagwort(e):
calorimetry
;
electrolyte-oxide interface
;
ion adsorption
Quelle:
Springer Online Journal Archives 1860-2000
Thema:
Chemie und Pharmazie
,
Physik
,
Werkstoffwissenschaften, Fertigungsverfahren, Fertigung
Notizen:
Abstract The theoretical description of the enthalpic effects accompanying ion adsorption at the oxide-electrolyte interface, developed recently by Rudzinski and co-workers, is used here to analyze the Kallay's experimental procedure of determining nonconfigurational heats of proton adsorption in a simple experiment involving use of titration calorimetry. That theoretical analysis, based on considering a certain real adsorption system, leads to important recommendation at which conditions the Kallay's titration experiment yields the most reliable figures describing the heats of proton adsorption.
Materialart:
Digitale Medien
URL:
http://dx.doi.org/10.1023/A:1008889818137
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