ISSN:
1600-5759
Source:
Crystallography Journals Online : IUCR Backfile Archive 1948-2001
Topics:
Chemistry and Pharmacology
,
Geosciences
,
Physics
Notes:
The structure of bis[μ-(9-hydroxy-1:2κ2O)-9-fluorenecarboxylato(2-)]-1κO; 2κO-bis[aqua(quinoline-κN)copper(II)] bis(dimethylformamide) dihydrate has been determined by single-crystal X-ray diffraction. The binuclear CuII unit comprises a pair of Cu atoms linked by two hydroxyl O-atom bridges. The coordination polyhedron around each Cu atom is a distorted square pyramid, the basal plane consisting of one N atom from the quinoline ligand, one carboxyl O atom and two bridging O atoms from two α-hydroxylated acid ligands, while the axial coordination site is occupied by an O atom of the coordinated water molecule with a Cu—O bond length of 2.424 (4) Å.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1107/S0108270195011474
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