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  • 11
    Electronic Resource
    Electronic Resource
    Springer
    Transition metal chemistry 24 (1999), S. 127-130 
    ISSN: 1572-901X
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology
    Notes: Abstract Reaction of potassium N-R-Sulfonyldithiocarbimates, K2(RSO2N=CS2) (R=Me, Ph, 4-MeC6H4, 2-MeC6H4, 4-ClC6H4, 4-BrC6H4), with CoCl2·6H2O, yielded the complex CoIII anions [Co(RSO2N=CS2)3]3-, which were isolated as their Bu4N+ salts. Elemental analyses, i.r. spectra and u.v.-vis. data were consistent with the formation of cobalt-sulfur diamagnetic octahedral (D3) complexes. The 1H and 13C n.m.r. spectra showed the expected signals for the Bu4N+ cation and the dithiocarbimate moieties. The 1H n.m.r. integrations were consistent with a 3:1 cation:anion ratio.
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  • 12
    ISSN: 1572-9001
    Keywords: Nickel complex ; dithiocarbimate ; sulfonamide ; crystal structure
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology
    Notes: Abstract Potassium N-4-methylphenylsulfonyldithiocarbimate, K2(4-CH3C6H4SO2N=CS2), reacted with nickel(II) chloride hexahydrate and tetrabutylammonium bromide to form the bis(N-4-methylphenylsulfonyldithiocarbimate)nickelate(II) tetrabutylammonium salt (Bu4N)2[Ni(4-CH3C6H4S2C=NSO2)2]. The elemental analyses, IR and UV-Vis data obtained were consistent with the formation of a $${\text{nickel}}{\kern 1pt} - {\kern 1pt} {\text{sulfur}}$$ diamagnetic planar complex. The 1H NMR and the 13C NMR spectra showed the expected signals for the dithiocarbimate moiety and the tetrabutylammonium cation. The single-crystal structure analysis showed that this substance crystallizes in the triclinic $${P\bar 1}$$ space group with a = 10.474(3) Å, b = 10.767(3) Å, c = 13.657(3) Å and α = 81.54(2)°, β = 80.44(2)°, γ = 67.63(2)°, V = 1398.5(8) Å3, and Z = 2. The nickel atom is coordinated to four sulfur atoms.
    Type of Medium: Electronic Resource
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  • 13
    Electronic Resource
    Electronic Resource
    Springer
    Journal of mammalian evolution 4 (1997), S. 119-144 
    ISSN: 1573-7055
    Keywords: marsupials ; jaw ; hearing ; mastication
    Source: Springer Online Journal Archives 1860-2000
    Topics: Biology
    Notes: Abstract A medial inflection of the mandibular angular process is present in most marsupials. The few living marsupials that lack this trait either are very specialized forms (e.g., Tarsipes) or show a medial inflection at some point in development that is lost in later ontogenetic stages (cf. Dactylopsila and Phascolarctos). A medially inflected angular process is not present in any known extant or extinct placental (including all Cretaceous taxa that preserve the back of the dentary bone). Some extant placentals with enlarged auditory bullae evolved a medial flange of the angular process as a strategy to increase gape, but this is not homologous to the marsupial condition. We conclude that the medially inflected angular process is a shared derived trait of extant and extinct marsupials. The significant diversity in the form of the medially inflected mandibular angular process in marsupials, documented here for 53 taxa, shows a general relation to dietary adaptations. Herbivores (with well-developed masseter and medial pterygoid muscles) tend to have a shelf-like angular process, while small, insectivorous marsupials generally have a rod-like angular process. A close connection between the angular process and the ectotympanic is maintained during early postnatal development in all marsupials examined, a relation not seen in the placentals examined. A previous hypothesis suggested that the angular process plays a role in hearing in pouch-young Monodelphis. Data on the maturation of the auditory system does not support this hypothesis. Currently there are no data on differences in muscular anatomy or mastication between marsupials and placentals that could serve as a causal explanation for the difference in adult form of the angular process between the two groups.
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  • 14
    Electronic Resource
    Electronic Resource
    Springer
    Journal of mammalian evolution 5 (1998), S. 113-126 
    ISSN: 1573-7055
    Keywords: homoplasy ; Mammalia ; phylogeny ; skeleton
    Source: Springer Online Journal Archives 1860-2000
    Topics: Biology
    Notes: Abstract It is commonly believed that there are differences in the evolutionary lability of the crania, dentition, and postcrania of mammals, the latter two being more prone to homoplasy because of strong selective pressures for feeding and locomotion, respectively. Further, because of the fragmentary nature of fossils, phylogenetic analyses of extinct taxa often must utilize characters based on only one of these systems. In this paper the levels of homoplasy (as measured by the consistency index; CI) were compared in characters based on these three anatomical systems in therian mammals. No statistically significant differences were found in the overall CIs of 41 data sets based on dental, cranial, or postcranial characters. Differences in homoplasy within data sets with two or three kinds of data were not statistically significant. These findings suggest that dental, cranial, and postcranial characters can be equally prone to homoplasy and none should be automatically dismissed, disregarded, or systematically weighted in phylogenetic analyses. The level of homoplasy in characters derived from a given region of the skeleton may differ depending on the taxonomic level of the taxa considered. Dental, cranial, and postcranial characters may not constitute “natural” classes, yet examination of the phylogenetic signal of these subsets of data previous to a simultaneous analysis can shed light on significant aspects of the evolutionary process.
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  • 15
    ISSN: 1573-8604
    Keywords: allogrooming ; Alouatta seniculus ; red howler ; social structure ; ectoparasites
    Source: Springer Online Journal Archives 1860-2000
    Topics: Biology
    Notes: Abstract We compare the allogrooming behavior of 5 troops (average size = 8.2) of red howlers (Alouatta seniculus) from the Venezuelan Llanos with that of other A. seniculus and Alouatta spp. of the genus. In 126.9 observation hr, we recorded 118 allogrooming events, with an average bout length of 109 sec. Females groomed more frequently than males did, but as groomees there is no significant differences between sexes. Adult males groomed adult females mostly in a sexual context (before copulation). Allogrooming rates differ significantly among groups. There are also significant differences among members of the same troop both as groomers and groomees, which we explain in the context of the social behavior and history of each troop. There is no significant correlation between weight of the groomee and duration of the grooming bout. However, the examination of grooming rates and ectoparasite load suggests that allogrooming may have hygienic consequences. Differences in allogrooming rates among species of Alouatta are related to differences in group kin structure and patterns of female competition, in particular, coalition formation. We conclude that the social structure and the degree of relatedness among individuals within a group (or among individuals in a population in interpopulation comparisons) is a more important determinant of allogrooming rate than body size or group size. Our results emphasize the importance of considering intergroup and interpopulational variation in behavior.
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  • 16
    Electronic Resource
    Electronic Resource
    Springer
    Hydrogeology journal 7 (1999), S. 180-187 
    ISSN: 1435-0157
    Keywords: Key words Argentina ; groundwater recharge/water budget ; numerical modeling ; conceptual model
    Source: Springer Online Journal Archives 1860-2000
    Topics: Geosciences
    Description / Table of Contents: Résumé Un modèle modulaire tridimensionnel (MODFLOW) a été utilisé pour simuler les écoulements souterrains dans le bassin de la rivière Azul (Province de Buenos Aires, Argentine), dans le but d'évaluer la justesse du modèle conceptuel du système hydrogéologique. La piézométrie simulée s'ajuste de façon satisfaisante à celle observée pour l'ensemble de la nappe. Les résultats du modèle indiquent que: (1) la recharge de la nappe n'est pas uniforme sur toute la région, mais qu'elle est mieux approchée par trois valeurs différentes, décroissant vers l'aval-gradient, en suivant la même distribution que les sols et les caractéristiques géomorphologiques; et (2) l'évapotranspiration est nettement plus importante que prévu initialement à partir de la méthode de Thornthwaite–Mather. Les valeurs d'évapotranspiration fournies par MODFLOW concordent bien avec les résultats d'autres études portant sur la région. Les résultats du modèle reproduisent convenablement les chroniques de débit des écoulements de surface, suggérant ainsi que la description par le modèle des relations rivière–nappe est correcte.
    Abstract: Resumen Se ha utilizado el modelo MODFLOW, del Servicio Geológico de los Estados Unidos, para simular el flujo de agua subterránea en la cuenca del arroyo del Azul, Provincia de Buenos Aires, Argentina, con el objeto de evaluar el modelo hidrogeológico conceptual. Los niveles hidráulicos simulados ajustan satisfactoriamente con los niveles observados. Los resultados de la simulación indican que: (1) la recarga no es uniforme, sino que puede caracterizarse con tres zonas en las que sus valores decrecen en la medida en que decrece la pendiente, que guarda similitud con la distribución de suelos y características geomorfológicas; y (2) la evapotranspiración sería mayor que la estimada en estudios previos, en los que se utilizó el método de Thornthwaite–Mather. La evapotranspiración estimada mediante la presente simulación concuerda con resultados de varios estudios independientes en la región. Respecto de la relación acuífero–río, existe un muy buen ajuste entre los aportes del acuífero al río simulados y los valores históricos de caudal base.
    Notes: Abstract  A three-dimensional modular model (MODFLOW) was used to simulate groundwater flow in the Azul River basin, Buenos Aires Province, Argentina, in order to assess the correctness of the conceptual model of the hydrogeological system. Simulated heads satisfactorily match observed heads in the regional water-table aquifer. Model results indicate that: (1) groundwater recharge is not uniform throughout the region but is best represented by three recharge rates, decreasing downgradient, similar to the distribution of soils and geomorphological characteristics; and (2) evapotranspiration rates are larger than previous estimates, which were made by using the Thornthwaite–Mather method. Evapotranspiration rates estimated by MODFLOW agree with results of independent studies of the region. Model results closely match historical surface-flow records, thereby suggesting that the model description of the aquifer–river relationship is correct.
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  • 17
    ISSN: 1572-9001
    Keywords: Nickel complex ; dithiocarbimate complex ; crystal structure of sulfonamide
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology
    Notes: Abstract The reaction of potassiumN-(methanesulfonyl)-dithiocarbimate, K2[S2C=NSO2CH3], with nickel(II) chloride hexahydrate, NiCl2·6H2O, formed the complex anion bis(N-(methanesulfonyl)-dithiocarbimate)nickelate(II), [Ni(S2C=NSO2CH3)2]2}-, which was isolated as its tetra-n-butylammonium salt. The UV-Vis data obtained were consistent with the formation of a nickelsulfur diamagnetic planar complex. The1H NMR and the13C NMR spectra showed the expected signals for then-Bu4N+ cation and the dithiocarbimate moiety. The single-crystal structure analysis showed that tetra-n-butylammonium bis(N-(methanesulfonyl)-dithiocarbimate)nickelate(II), (Bu4N)2[Ni(S2C=NSO2CH3)2], crystallizes in the monoclinic space groupP2l/c witha=9.3197(5),b=15.0795(8),c=17.5286(9) å,Β=91.262(3)
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  • 18
    Electronic Resource
    Electronic Resource
    New York, N.Y. : Wiley-Blackwell
    Journal of Cellular Biochemistry 49 (1992), S. 172-180 
    ISSN: 0730-2312
    Keywords: HMG proteins ; Schistosoma mansoni ; sex-specific gene ; DNA binding ; regulation ; Life and Medical Sciences ; Cell & Developmental Biology
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Biology , Chemistry and Pharmacology , Medicine
    Notes: A pool of nuclear proteins from adult worms of Schistosoma mansoni was analyzed for amino acid composition and found to be compatible with high mobility group (HMG) proteins. One of the schistosome HMG proteins was identified as HMG 2 by one-dimensional and two-dimensional PAGE. Stage-specific differences in the HM-like protein composition were encountered when adult worms were compared to schistosomula, the larval form. Immobilization of the adult male and female nuclear proteins onto nitrocellulose, followed by hybridization against 32P-F-10, a schistosome sex specific gene encoding a major egg shell protein, revealed distinct banding patterns. On the other hand, a synthetic oligonucleotide, derived from the 3′untranslated end of the F-10 gene and possibly containing one regulatory element of the gene, bound mainly to male low MW proteins.
    Additional Material: 6 Ill.
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  • 19
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    Unknown
    PANGAEA
    In:  Instituto del Mar del Peru
    Publication Date: 2024-03-26
    Keywords: CENSOR; Climate variability and El Niño Southern Oscillation; DATE/TIME; Historical_Peru; Landings in mass; LATITUDE; LONGITUDE; MON; Monitoring; Peru_landing; Peru Continental Margin; Species; Species, common name
    Type: Dataset
    Format: text/tab-separated-values, 2916 data points
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  • 20
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    Unknown
    PANGAEA
    In:  Instituto del Mar del Peru
    Publication Date: 2024-03-26
    Keywords: CENSOR; Climate variability and El Niño Southern Oscillation; DATE/TIME; Historical_Peru; Landings in mass; LATITUDE; LONGITUDE; MON; Monitoring; Name; Peru_landing; Peru Continental Margin
    Type: Dataset
    Format: text/tab-separated-values, 1896 data points
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