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  • 11
    Electronic Resource
    Electronic Resource
    Bognor Regis [u.a.] : Wiley-Blackwell
    Journal of Polymer Science Part B: Polymer Physics 29 (1991), S. 161-170 
    ISSN: 0887-6266
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Physics
    Notes: The phase behavior of narrow molecular weight distribution samples of polystyrene and polyisoprene in the presence of toluene was investigated by means of gel permeation chromatography. Equilibrium phase diagrams, tie lines, and critical points for a number of partially miscible polystyrene-polyisoprene-toluene systems were generated at 15 and 30°C and 1 atm pressure. The data were combined with previously reported results at 45°C. Using the experimentally determined phase compositions along with literature values of the polymer-solvent interaction parameters, the polymer-polymer interaction parameters were evaluated using the Flory-Huggins theory. The influence of temperature, polymer molecular weight, and polymer-solvant interaction parameters on the size, shape, and location of the equilibrium phase curve, the location of the critical point, and the polymer-polymer interaction parameter was studied.
    Additional Material: 3 Ill.
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  • 12
    Electronic Resource
    Electronic Resource
    Stamford, Conn. [u.a.] : Wiley-Blackwell
    Polymer Engineering and Science 25 (1985), S. 934-941 
    ISSN: 0032-3888
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: The equilibrium phase behavior of the partially miscible system polystyrene-polybutadiene-chloroform was studied at 25°C and 1 atm pressure by using gel permeation chromatography to analyze the conjugate phases. Three narrow molecular weight distribution samples of each polymer were used to provide nine examples of the system for study. The Flory-Huggins theory was used to determine the polymer-polymer interaction parameter χ23, When literature values of the two polymer-solvent interaction parameters χ12 and χ13 were used, the χ23 values generally were found to be negative and to show no distinct concentration dependence. No significant improvement was found when the literature value of only the polybutadiene-chloroform interaction parameter was used to simultaneously generate values of χ23 and χ12. Values of χ23 at the critical point, χ23,cr, were found to increase with increasing polymer concentration.
    Additional Material: 4 Ill.
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  • 13
    Electronic Resource
    Electronic Resource
    New York, NY [u.a.] : Wiley-Blackwell
    Journal of Applied Polymer Science 19 (1975), S. 2859-2868 
    ISSN: 0021-8995
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: The evaporation of the solvent 1,2,3,4-tetrahydronaphthalene from the ternary system polystyrene/polybutadiene/tetrahydronaphthalene was studied. Ternary solutions of precisely known weight concentrations were prepared and then dried under vacuum and elevated temperatures. When the solution was assumed completely dried to a solid, the solvent content was calculated by difference. The deviation between the two solvent contents, namely, that known by exact weighing of components and that calculated after drying, was found to be significant, the reason for this discrepancy resting in the fact that solvent is assumed entrapped in the polystyrene fraction of the polymer residue. The possibility of the formation of interpenetrating networks causing this solvent entrapment is discussed as is a possible means of achieving more efficient solvent evaporation.
    Additional Material: 6 Ill.
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  • 14
    Electronic Resource
    Electronic Resource
    New York, NY [u.a.] : Wiley-Blackwell
    Journal of Applied Polymer Science 22 (1978), S. 593-596 
    ISSN: 0021-8995
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Additional Material: 3 Ill.
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  • 15
    Electronic Resource
    Electronic Resource
    New York, NY [u.a.] : Wiley-Blackwell
    Journal of Applied Polymer Science 30 (1985), S. 307-315 
    ISSN: 0021-8995
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: Solubility data of organic probes in polydimethylsiloxane (PDMS) and polyisobutylene (PIB) obtained by inverse gas chromatography (IGC) were collected from the literature and analyzed. Applying the principle of corresponding states, empirical correlations were derived and presented for the estimation of solubilities of nonpolar and slightly polar probe molecules in these polymers. Estimation of other thermodynamic properties, such as activity coefficient of the solute, Henry's law constant, Flory-Huggins interaction parameter, and heat of solution through the use of these correlation equations, was demonstrated.
    Additional Material: 3 Ill.
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  • 16
    Electronic Resource
    Electronic Resource
    New York, NY [u.a.] : Wiley-Blackwell
    Journal of Applied Polymer Science 23 (1979), S. 749-754 
    ISSN: 0021-8995
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: Gel permeation chromatography using sequential differential refractive index and ultraviolet detectors has been successfully used to give the compositional analysis of conjugate phases in the incompatible system of polystyrene and polybutadiene with tetrahydrofuran as solvent. Application of this method to equilibrated samples yields tie lines, binodal curves, and plait points. The effects of molecular weights and molecular weight ratios on the slopes of the tie lines, the location of the binodal curve, and the depletion of second polymers from phases are discussed.
    Additional Material: 2 Ill.
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  • 17
    Electronic Resource
    Electronic Resource
    New York : Wiley-Blackwell
    Journal of Polymer Science: Polymer Chemistry Edition 17 (1979), S. 3459-3472 
    ISSN: 0360-6376
    Keywords: Physics ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: A means of coupling synthetic polymers of biomedical interest with collagen under mild conditions was investigated as a part of preliminary studies in the development of a biomedical adhesive. The coupling agent, 1-cyclohexyl-3-[2-morpholinyl-(4)-ethyl]carbodiimide, provides a covalent bond between the acrylic polymer and collagen. The variables affecting the establishment of this bond in solution are concentration of the carboxylic group on the acrylic polymer, concentration of the acid-soluble collagen, concentration of the coupling agent, pH, and time of reaction. Optimum values of these variables have been obtained experimentally.
    Additional Material: 7 Ill.
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  • 18
    Electronic Resource
    Electronic Resource
    New York : Wiley-Blackwell
    Journal of Polymer Science: Polymer Chemistry Edition 17 (1979), S. 3473-3483 
    ISSN: 0360-6376
    Keywords: Physics ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: The coupling mechanism involved in the coupling of acrylic polymers and collagen by a water-soluble carbodiimide was investigated. By the use of a series of homopolymers of α-amino acids, support was given to the postulate that a major proportion of the coupling takes place in the amino functional group. In light of the results presented the reaction is sterically controlled and the steric, stoichiometric, and kinetic aspects of the reaction are discussed.
    Additional Material: 3 Tab.
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  • 19
    Electronic Resource
    Electronic Resource
    New York : Wiley-Blackwell
    Journal of Polymer Science: Polymer Letters Edition 19 (1981), S. 299-301 
    ISSN: 0360-6384
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Additional Material: 1 Ill.
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  • 20
    Publication Date: 2013-03-01
    Print ISSN: 0167-577X
    Electronic ISSN: 1873-4979
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Published by Elsevier
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