Digitale Medien
College Park, Md.
:
American Institute of Physics (AIP)
The Journal of Chemical Physics
82 (1985), S. 3491-3501
ISSN:
1089-7690
Quelle:
AIP Digital Archive
Thema:
Physik
,
Chemie und Pharmazie
Notizen:
Using the radiation of several ion laser lines and of a tunable dye laser, the first gas phase spectra of the MgCa molecule have been obtained. The laser induced fluorescence spectra have been assigned to the A 1Σ+–X 1Σ+, B 1Π–X 1Σ+, and the C 1Σ+–X 1Σ+ systems. The quantum numbers of the levels belonging to the X 1Σ+ ground state were determined using a quantum mechanical, variational method. The vibrational quantum numbers of the excited levels and the assignment to the different electronic states were obtained from a comparison of the measured and calculated Franck–Condon factors which are in very good agreement.
Materialart:
Digitale Medien
URL:
http://dx.doi.org/10.1063/1.448929
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