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  • 1
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    Detection of abundant ethane and methane, along with carbon monoxide and water, in comet C/1996 B2 Hyakutake: evidence for interstellar origin (1996)
    In:  Other Sources
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    Publication Date: 2011-08-24
    Description: The saturated hydrocarbons ethane (C2H6) and methane (CH4) along with carbon monoxide (CO) and water (H2O) were detected in comet C/1996 B2 Hyakutake with the use of high-resolution infrared spectroscopy at the NASA Infrared Telescope Facility on Mauna Kea, Hawaii. The inferred production rates of molecular gases from the icy, cometary nucleus (in molecules per second) are 6.4 X 10(26) for C2H6, 1.2 X 10(27) for CH4, 9.8 X 10(27) for CO, and 1.7 X 10(29) for H2O. An abundance of C2H6 comparable to that of CH4 implies that ices in C/1996 B2 Hyakutake did not originate in a thermochemically equilibrated region of the solar nebula. The abundances are consistent with a kinetically controlled production process, but production of C2H6 by gas-phase ion molecule reactions in the natal cloud core is energetically forbidden. The high C2H6/CH4 ratio is consistent with production of C2H6 in icy grain mantles in the natal cloud, either by photolysis of CH4-rich ice or by hydrogen-addition reactions to acetylene condensed from the gas phase.
    Keywords: Lunar and Planetary Science and Exploration
    Type: Science (ISSN 0036-8075); Volume 272; 5266; 1310-4
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  • 2
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    Intensities and broadening coefficients for the Q branch of the 4nu-2 - nu-1 + nu-2 (471.511/cm) band of CO2 (1993)
    In:  Other Sources
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    Publication Date: 2011-08-24
    Description: Absolute intensities for the Q-branch of the 4nu-2 - nu-1 + nu-1/2 (20,003-11,101) band in CO2 were measured for the first time. Measurements were performed for lines Q10 to Q28, at temperatures ranging from 385 to 426 K, for pressures from 3 to 40 torr, using our long wavelength tunable diode laser spectrometer. The combination of tunable diode lasers, a White cell, and a blocked impurity band detector made it possible to obtain signal to noise ratios greater than 1000 in the 471/cm spectral region, with about 3 x 10 exp -4/cm spectral resolution. The band strength was found to be 8.6(2) x 10 exp -25 cm/molec at 296 K, and the Hermann-Wallis factor was determined. Comparison with the values listed in the HITRAN 92 data base are presented. Self-, N2- and O2-broadening coefficients were also measured.
    Keywords: ATOMIC AND MOLECULAR PHYSICS
    Type: Journal of Quantitative Spectroscopy & Radiative Transfer (ISSN 0022-4073); 50; 2; p. 193-198.
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  • 3
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    Detection of atomic deuterium in the upper atmosphere of Mars (1998)
    In:  Other Sources
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    Publication Date: 2011-08-24
    Description: High-resolution spectroscopy of Mars' atmosphere with the Hubble Space Telescope revealed the deuterium Lyman alpha line at an intensity of 23 +/- 6 rayleighs. This measured intensity corresponds to HD/H2 = 1.5 +/- 0.6 x 10(-4), which is smaller by a factor of 11 than HDO/H2O. This indicates that fractionation of HD/H2 relative to that of HDO/H2O is not kinetically controlled by the rates of formation and destruction of H2 and HD but is thermodynamically controlled by the isotope exchange HD + H2O left and right arrow HDO + H2. Molecular hydrogen is strongly depleted in deuterium relative to water on Mars because of the very long lifetime of H2 (1200 years). The derived isotope fractionation corresponds to an estimate of a planetwide reservoir of water ice about 5 meters thick that is exchangeable with the atmosphere.
    Keywords: Lunar and Planetary Science and Exploration
    Type: Science (ISSN 0036-8075); Volume 280; 5369; 1576-80
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  • 4
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    Spectroscopic planetary detection (1986)
    In:  CASI
    Details
    Publication Date: 2006-02-14
    Description: The Sun-as-a-star was monitored using the McMath Fourier transform spectometer (FTS) on Kitt Peak in 1983. In 1985 the first measurement was made using the laser heterodyne technique. The FTS measurements now extend for three years, with errors of order 3 meters/sec at a given epoch. Over this 3 year period, a 33 meter/sec change was measured in the apparent velocity of integrated sunlight. The sense of the effect is that a greater blueshift is seen near solar minimum, which is consistent with expectations based on considering the changing morphology of solar granular convection. Presuming this effect is solar-cycle-related, it will mimic the Doppler reflex produced by a planetary companion of approximately two Jupiter masses, with an 11 year orbital period. Thus, Jupiter itself is below the threshold for detection by spectroscopic means, without an additional technique for discrimination. However, for planetary companions in shorter period orbits (P approx. 3 years) the threshold for unambiguous detection is well below one Jupiter mass.
    Keywords: ASTRONOMY
    Type: NASA, Washington Reports of Planetary Astronomy, 1985; p 143-144
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  • 5
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    Advanced infrared astronomy (1986)
    In:  CASI
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    Publication Date: 2006-02-14
    Description: The CO2 laser heterodyne spectrometer was used at the 3-m IRTF on Mauna Kea to make measurements of Mars during the 1984 opposition. Analysis of the observations of the mesospheric non-thermal emission demonstrated the existence of a warming of the Mars polar mesosphere, similar to the seasonal effects which are well known to occur at the Earth's mesopause. A search for CO2 and NH3 on Comet Halley was done with the new Kitt Peak system as well as with the IRTF heterodyne system. A Lamb-dip absorption cell was designed and constructed. Its use will allow extreme frequency stabilization of the laser local oscillator, which will greatly facilitate measurements of winds and dynamical phenomena. The Lamb-dip cell was used at Kitt Peak to study zonal and meridional winds in the atmosphere of Venus. Water vapor was detected in Comet Halley using Fourier transform spectrometer. The 2.65 micrometer upsilon sub 3 band was seen in emission, confirming non-thermal-equilibrium excitation models for comets. A study was made of the variability of Jovian ethane emission. The average volume mixing ratio of ethane in the Jovian stratosphere was found to be 3x10 to the -6 power, with the greatest variability seen in the auroral regions.
    Keywords: ASTRONOMY
    Type: NASA, Washington Reports of Planetary Astronomy, 1985; p 11-13
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  • 6
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    Infrared spectral measurement of Space Shuttle glow (1992)
    In:  Other Sources
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    Publication Date: 2011-08-24
    Description: The USAF and NASA successfully conducted infrared spectral measurements of the Space Shuttle glow during STS-39. Preliminary analysis indicates that NO, NO(+), OH, and CO produce infrared glow during quiescent orbiter conditions. During orbiter thruster firings the glow intensities in the infrared are enhanced by factors of 10X and 100X with significant changes in spectral distribution. These measurements were obtained with the Spacecraft Kinetic Infrared Test payload which included a cryogenic infrared circular variable filter infrared spectrometer covering the 0.7 to 5.4 microns wavelength region. Approximately 14,000 spectra of Shuttle glow, airglow, aurora, and the orbiter environment were obtained during the eight day mission. The STS-39 Space Shuttle Discovery was launched from the NASA Kennedy Space Center on 28 April, 1991 into a 57-deg inclination circular orbit at an altitude of 260 km.
    Keywords: SPACECRAFT DESIGN, TESTING AND PERFORMANCE
    Type: Geophysical Research Letters (ISSN 0094-8276); 19; 10, M
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  • 7
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    New features in Saturn's atmosphere revealed by high-resolution thermal infrared images (1989)
    In:  Other Sources
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    Publication Date: 2011-08-19
    Description: Observations of the stratospheric IR emission structure on Saturn are presented. The high-spatial-resolution global images show a variety of new features, including a narrow equatorial belt of enhanced emission at 7.8 micron, a prominent symmetrical north polar hotspot at all three wavelengths, and a midlatitude structure which is asymmetrically brightened at the east limb. The results confirm the polar brightening and reversal in position predicted by recent models for seasonal thermal variations of Saturn's stratosphere.
    Keywords: LUNAR AND PLANETARY EXPLORATION
    Type: Nature (ISSN 0028-0836); 342; 777-780
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  • 8
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    Nonthermal rotational distribution of CO/A 1Pi/ fragments produced by dissociative excitation of CO2 by electron impact (1975)
    In:  Other Sources
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    Publication Date: 2011-08-16
    Description: Measurements were made of the rotational profiles of specific bands of the CO fourth-positive group (4PG). The CO 4PG bands were excited by electron impact dissociative excitation of CO2. The results are applicable to analysis of the Mariner observations of the CO 4PG in the dayglow of Mars. The results indicate that dissociative excitation of CO2 by electron impact leads to CO(A 1Pi) fragments with a rotational distribution that is highly nonthermal. The parent CO2 temperature was about 300 K in the experiment, while the fragment CO(A 1Pi) showed emission band profiles consistent with a rotational temperature greater than about 1500 K. Laboratory measurement of the reduced transmission of the hot bands by thermal CO appears to be the most direct way of determining the column density responsible for the CO(v',0) absorption of Mars.
    Keywords: LUNAR AND PLANETARY EXPLORATION
    Type: Journal of Geophysical Research; 80; Jan. 1
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  • 9
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    Angular distributions and polarization fractions of helium resonance radiation /n 1P-1 1S/ in the extreme ultraviolet (1974)
    In:  Other Sources
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    Publication Date: 2011-08-16
    Description: Angular intensity distributions of helium resonance photons, experimentally determined for the first time with respect to the exciting electron beam, are presented. The angular intensity distributions were measured at selected electron-impact energies from 25 to 150 eV. The results obtained are slightly higher than theoretical data for electron impact energies from 80 to 150 eV.
    Keywords: PHYSICS, ATOMIC, MOLECULAR, AND NUCLEAR
    Type: Physical Review A - General Physics; vol. 9
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  • 10
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    Effect of electron beam pulse width on time-of-flight spectra (1974)
    In:  Other Sources
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    Publication Date: 2011-08-16
    Description: A simple but useful formula describing the effect of electron gun pulse width on the time of flight (TOF) spectra measured in translational spectroscopy experiments is developed. An approximately monoenergetic pulsed electrostatically focused electron beam traverses a scattering cell filled with a Maxwellian gas. Inelastic electron collisions with the gas produce metastable particles, ions, scattered electrons, and photons which then pass through a collimating slit system at right angles to the electron beam. TOF techniques are used to separate the photon signal from the metastable particle signal and to measure the TOF distribution of the metastable species.
    Keywords: INSTRUMENTATION AND PHOTOGRAPHY
    Type: Review of Scientific Instruments; 45; Feb. 197
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