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  • 1
    Publication Date: 2021-07-21
    Description: Since its recognition as an impact structure 60 years ago, no volcanics were anticipated in the circular depression of the 14.8 Ma old Nördlinger Ries. Here, we describe for the first time a volcanic ash‐derived clinoptilolite‐heulandite‐buddingtonite bed within the 330 m thick Miocene lacustrine crater fill. Zircon U‐Pb ages of 14.20 ± 0.08 Ma point to the source of the volcanic ash in the Pannonian Basin, 760 km east of the Ries. The diagenetically derived zeolite‐feldspar bed occurs in laminated claystones of the Ries soda‐lake stage and represents the first unequivocal stratigraphic marker bed in this basin, traceable from marginal surface outcrops to 218 m below surface in the crater center. These relationships demonstrate a deeply bowl‐shaped geometry of crater fill sediments, not explainable by sediment compaction and corresponding stratigraphic backstripping alone. Since most of the claystones formed at shallow water depths, the bowl‐shaped geometry must reflect 134 +23/−49 m of sagging of the crater floor. We attribute the sagging to compaction and closure of the dilatant macro‐porosity of the deeply fractured and brecciated crater floor during basin sedimentation and loading, a process that lasted for more than 0.6 Myr. As a result, the outcrop pattern of the lithostratigraphic crater‐fill units in its present erosional plane forms a concentric pattern. Recognition of this volcanic ash stratigraphic marker in the Ries crater provides insights into the temporal and stratigraphic relationships of crater formation and subsidence that have implications for impact‐hosted lakes on Earth and Mars.
    Description: Plain Language Summary: We describe for the first time a volcanic ash layer from the lake sediment fill of the 14.8 million years old asteroid impact crater Nördlinger Ries. Radiometric age and trace element characteristics of this ash layer are identical to that of a volcanic field in Hungary, so that the ash reflects a volcanic eruption 760 km east of the Ries basin. Recognition of this ash layer enables its use as a marker bed. The ash layer can be traced from surface outcrops to 218 m depth in drillings. This indicates that the strata are significantly inclined toward the crater center. Calculations of sediment compaction by further sediment load and burial only partially explain the observed deeply bowl‐shaped geometry. We attribute the additional sagging to the subsidence of the crater floor substrate, formed of rocks highly shattered by the impact event. Both effects cause a concentric pattern of outcropping strata in the partially eroded crater fill. The presence of the ash layer and its use to help disentangle the source and timing of subsidence (due to compaction of lake sediments, and closure of deeper, impact‐induced fractures), has important implications for lakes formed in impact craters on Earth and Mars.
    Description: Key Points: A critical question in the evolution of impact‐crater‐hosted lakes is the origin and timing of post‐impact floor subsidence We describe a volcanic ash layer from the Ries impact crater that demonstrates a deeply bowl‐shaped geometry of its lacustrine crater fill This geometry, leading to a concentric outcrop pattern, requires significant crater floor sagging, in addition to sediment compaction
    Description: German Research Foundation
    Description: Chinese Scholarship Council
    Description: Bolyai J. Research Fellowship
    Keywords: 554.3 ; impact structure ; sediment basin ; subsidence ; volcanic ash
    Type: article
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  • 2
    Publication Date: 2024-02-07
    Description: Extensive and protracted volcanism in the Carpathian-Pannonian Region climaxed during the Early to Middle Miocene with series of major ignimbrite-forming eruptions with their products dispersed across the Alpine-Mediterranean Region. The spatial and temporal dispersion of these volcanic horizons make them potentially important stratigraphic markers throughout the region, allowing better understanding of temporal and spatial changes in depositional environments and paleoclimate. Several of these Middle Miocene volcaniclastic layers are preserved in stratigraphically and environmentally variable sedimentary facies on Mt. Medvednica, located in the North Croatian Basin. In order to decipher the age, depositional environment and provenance of two volcaniclastic horizons intercalated within Central Paratethys marine sediments on Mt. Medvednica, we applied an integrated approach of volcanological, geochronological, and paleontological analyses. New high-precision zircon geochronology and volcanic glass geochemistry data allow to distinguish two primary rhyolitic volcaniclastic horizons derived from distinct eruptions, “Plaz“, and the “Bidrovec“, dated at 14.937 ± 0.012 Ma and 14.835 ± 0.012 Ma. Distinguished mineralogical and geochemical data enabled the correlation of the older (“Plaz”) horizon on Mt. Medvednica with the Demjén eruption, one of the six major Early–Middle Miocene ignimbrite-forming eruptions of the Carpathian-Pannonian Region. However, a correlation of the younger (“Bidrovec“) horizon and assignment to a specific eruption could not be established due to a lack of compositional data from coeval eruption products throughout the region. The newly gathered data establishes both “Plaz” and “Bidrovec” pyroclastic deposits as valuable marker horizons for regional reconstructions, and enable a better understanding of the eruption chronology and tephrostratigraphy of the Carpathian-Pannonian Region.
    Type: Article , PeerReviewed
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  • 3
    Publication Date: 2024-02-07
    Description: The Carpathian-Pannonian Region (CPR) hosted some of the largest silicic volcanic eruptions in Europe during the Early and Middle Miocene, contemporaneously with major lithospheric thinning of the Pannonian Basin. This was recorded as an ignimbrite flare-up event from approximately 18.1–14.4 Ma. To gain in-depth perspectives on the eruption chronology, tephrostratigraphy, and petrogenesis at the onset of CPR silicic volcanism, we applied a multi-proxy approach to Lower Miocene rhyolitic ignimbrites and pyroclastic fall deposits from the northern CPR to the Dinaride Lake System. High-precision zircon U-Pb geochronology distinguished two Lower Miocene groups of volcaniclastic rocks at ∼ 18.1 Ma and ∼ 17.3 Ma. Based on combined tephrostratigraphic signatures we propose that the ∼ 18.1 Ma Kalnik and ∼ 17.3 Ma Eger eruptions produced widespread (intermediate to) large caldera-forming massive rhyolitic ignimbrites, deposited across northern and southwestern regions of the CPR. Due to easterly winds that carried volcanic ash hundreds of kilometers to the southwest, Eger eruption products also reached distal intra-montane Dinaride lacustrine basins, recorded as pyroclastic fall deposits. Heterogeneous major and trace elemental compositions of ∼ 18.1 Ma volcanic glass shards suggest that the Kalnik eruption was sourced from complex silicic magmatic systems, with simultaneous tapping of two discrete melt bodies during the eruption. The homogeneous geochemical composition of ∼ 17.3 Ma glasses is distinct from the older glasses. Integrated zircon and bulk glass Nd-Hf isotope compositions have a positive correlation, defining a regional mantle array, and are more radiogenic in the younger phase of volcanism. The recorded systematic isotopic change, moving from older more crustal signatures to younger more juvenile compositions, imply that during the period of lithospheric thinning of the Pannonian Basin the region underwent more complex variations in the interaction between metasomatized lithospheric mantle-derived magmas and various crustal components than previously recognized.
    Type: Article , PeerReviewed
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  • 4
    Publication Date: 2024-04-03
    Description: Highlights • Four rhyolitic explosive eruption events were distinguished from 13.1 Ma to 11.6 Ma. • Silicic volcanism occurred at termination of subduction in a thinning lithosphere. • Rhyolites show extreme magma differentiation and reduced-dry character. • Zircon trace element and Hf isotope fingerprint is an effective correlation tool. Abstract The Tokaj Mts. volcanism occurred in a thinning continental lithosphere regime at the final stage of the subduction process. Using high-precision zircon U-Pb dating, four major explosive eruption events were distinguished. Among them the 13.1 Ma Sátoraljaújhely and the 12.0 Ma Szerencs eruptions could have yielded large amount of volcanic material (possibly 〉 100 km3) and they were associated with caldera collapse as shown by the several hundred-metre-thick pyroclastic deposits and the long (〉100 km) runout pyroclastic flow in case of the 13.1 Ma eruption. The 12.3 Ma Hegyköz and the 11.6 Ma Vizsoly eruptions were relatively smaller. The volcanic products can be readily distinguished by zircon and glass trace elements and trace element ratios, which can be used for fingerprinting and to correlate with distal deposits. The Rb, Ba, Sr content and strong negative Eu-anomaly of the glasses reflect extreme crystal fractionation, particularly for the Szerencs rhyolitic magma. The silicic volcanic products of the Tokaj Mts. show compositional similarities with the so-called ‘dry–reduced–hot’ rhyolite type consistent with an origin in an extensional environment, where the primary magmas were formed by near-adiabatic decompression melting in the mantle with subordinate fluid flux. In contrast, some of the older Bükkalja rhyolitic magmas evolved via more hydrous evolutionary paths, where amphibole played a role in the control of the trace element budget. The significant increase of zircon ε Hf values from −8.8 to + 0.2 in the rhyolitic pyroclastic rocks of Tokaj Mts. with time implies that mantle-derived magmas became more dominant. This can be explained by the specific tectonic setting, i.e. the final stage of subduction when the descending subducted slab became almost vertical, which exerted a pull in the upper lithosphere leading to thinning and accelerated subsidence as well as asthenospheric mantle flow just before the slab detachment.
    Type: Article , PeerReviewed
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