ALBERT

Description: Volatile compounds in comets are the most pristine materials surviving from the time of formation of the Solar System, and thus potentially provide information about conditions that prevailed in the primitive solar nebula. Moreover, comets may have supplied a substantial fraction of the volatiles on the terrestrial planets, perhaps including organic compounds that played a role in the origin of life on Earth. Here we report the detection of hydrogen isocyanide (HNC) in comet Hyakutake. The abundance of HNC relative to hydrogen cyanide (HCN) is very similar to that observed in quiescent interstellar molecular clouds, and quite different from the equilibrium ratio expected in the outermost solar nebula, where comets are thought to form. Such a departure from equilibrium has long been considered a hallmark of gas-phase chemical processing in the interstellar medium, suggesting that interstellar gases have been incorporated into the comet's nucleus, perhaps as ices frozen onto interstellar grains. If this interpretation is correct, our results should provide constraints on the temperature of the solar nebula, and the subsequent chemical processes that occurred in the region where comets formed.

Description: Rotational spectroscopy at millimeter wavelengths is a powerful means of investigating the chemistry of dense interstellar clouds. These regions can exhibit an interesting complement of gas phase molecules, including relatively complex organics. Here we report the tentative first astronomical detection of aziridine (ethylenimine), the possible detection of propenal (acrolein), and upper limits on the abundances of cyclopropenone, furan, hydroxyethanal (glycolaldehyde), thiohydroxylamine (NH2SH), and ethenol (vinyl alcohol) in various interstellar clouds.

Description: The abundance ratio of the isomers HCN and HNC has been investigated in comet Hale-Bopp (C/1995 O1) through observations of the J = 4-3 rotational transitions of both species for heliocentric distances 0.93 〈 r 〈 3 AU, both pre- and post-perihelion. After correcting for the optical depth of the stronger HCN line, we find that the column density ratio of HNC/HCN in our telescope beam increases significantly as the comet approaches the Sun. We compare this behavior to that predicted from an ion-molecule chemical model and conclude that the HNC is produced in significant measure by chemical processes in the coma; i.e., for comet Hale-Bopp, HNC is not a parent molecule sublimating from the nucleus.

Description: We review the nature of the widespread organic material present in the Milky Way Galaxy and in the Solar System. Attention is given to the links between these environments and between primitive Solar System objects and the early Earth, indicating the preservation of organic material as an interstellar cloud collapsed to form the Solar System and as the Earth accreted such material from asteroids, comets and interplanetary dust particles. In the interstellar medium of the Milky Way Galaxy more than 100 molecular species, the bulk of them organic, have been securely identified, primarily through spectroscopy at the highest radio frequencies. There is considerable evidence for significantly heavier organic molecules, particularly polycyclic aromatics, although precise identification of individual species has not yet been obtained. The so-called diffuse interstellar bands are probably important in this context. The low temperature kinetics in interstellar clouds leads to very large isotopic fractionation, particularly for hydrogen, and this signature is present in organic components preserved in carbonaceous chondritic meteorites. Outer belt asteroids are the probable parent bodies of the carbonaceous chondrites, which may contain as much as 5% organic material, including a rich variety of amino acids, purines, pyrimidines, and other species of potential prebiotic interest. Richer in volatiles and hence less thermally processed are the comets, whose organic matter is abundant and poorly characterized. Cometary volatiles, observed after sublimation into the coma, include many species also present in the interstellar medium. There is evidence that most of the Earth's volatiles may have been supplied by a 'late' bombardment of comets and carbonaceous meteorites, scattered into the inner Solar System following the formation of the giant planets. How much in the way of intact organic molecules of potential prebiotic interest survived delivery to the Earth has become an increasingly debated topic over the last several years. The principal source for such intact organics was probably accretion of interplanetary dust particles of cometary origin.

Description: Significant gas-phase chemistry occurs in the comae of bright comets, as is demonstrated here for the case of Comet Hale-Bopp. The abundance ratio of the two isomers, hydrogen cyanide and hydrogen isocyanide, is shown to vary with heliocentric distance in a way that is consistent with production of HNC by ion-molecule chemistry initiated by the photoionization of water. Likewise, the first maps of emission from HCO+ show an abundance and an extended distribution that are consistent with the same chemical model.

Description: Some 34 radio observatories in 18 countries are participating in the Radio Science Net of the International Halley Watch. Approximately 100 radio astronomers are contributing to this effort, which has included observations of comets P/Crommelin and P/Giacobini-Zinner as well as P/Halley. It is clear that the record of data for the 18 cm OH ground state lambda doublet, which provides fundamental information on the gas production rate, kinematics, and potentially the magnetic field in the coma, will be vastly more complete and of higher accuracy than has even been obtained on any previous comet. The coverage by a number of radio observatories will enable short period variations to be studied and correlated with simultaneous data obtained at other wavelengths. Likewise, the first definitive detection of the important parent molecule hydrogen cyanide in a comet was obtained and is being studied by groups in the United States, Sweden, and France. The first detection of the comet with the Very Large Array telescope operated by NRAO was achieved and has produced exciting results for the distribution of emission at high angular resolution from the OH radical. At this writing data are still being obtained and being processed, and there are still strong indications that exciting information will be obtained from radar studies of P/Halley and from searches for additional parent molecules.

Description: The research effort was concentrated toward comet P/Halley, although observations of other comets including Giacobini-Zinner, Hartley-Good and Thiele were made as opportunities arise. In preparing for the apparition of P/Halley, detailed predictions for the emission in the 18 cm OH transitions were made in order to assist observers and to indicate what type of data would be particularly valuable. Likewise, since occultations by the comet of background radio sources can provide unique types of information, the tracks of P/Halley and P/Giacobini-Zinner were surveyed with the NRAO Very Large Array, background sources were mapped, and a catalogue of occulted sources published. Beginning in September, 1985, regular observations of the 18 cm OH lines have been made for P/Halley using the 43 m antenna of the NRAO in Greenbank, West Virginia. These data promise to provide the most accurate time sequence for the OH emission for any comet ever obtained at radio wavelengths. From the linewidth and shape, information is obtained on the kinetics of the gas in the cometary coma. An extensive series of observations have been undertaken with 14 m antenna to study emission from the HCN molecule in P/Halley. These data provide the first definitive detection of this component of the cometary ices. Interesting variations in the production of HCN were observed with time scales less than a day. Likewise, there appeared to be variations in the ratio of the hyperfine components of the J = 1-0 transition.

Description: The present research includes searches for important new interstellar constituents; observations relevant to differentiating between different models for the chemical processes that are important in the interstellar environment; and coordinated studies of the chemistry, physics, and dynamics of molecular clouds which are the sites or possible future sites of star formation. Recent research has included the detection and study of four new interstellar molecules; searches which have placed upper limits on the abundance of several other potential constituents of interstellar clouds; quantitative studies of comparative molecular abundances in different types of interstellar clouds; investigation of reaction pathways for astrochemistry from a comparison of theory and the observed abundance of related species such as isomers and isotopic variants; studies of possible tracers of energenic events related to star formation, including silicon and sulfur containing molecules; and mapping of physical, chemical, and dynamical properties over extended regions of nearby cold molecular clouds.

Description: Continuum and spectral-line radio observations of the comets IRAS-Araki-Alcock and Sugano-Saigusa-Fujikawa obtained at a number of observatories during May and June, 1983, are compiled in tables and briefly characterized. The species NH3, H2O, CO, and HCN are considered in detail; visible-range observations of CN are compared; and the implications of the results and the experience gained in performing and coordinating the observations for the detection of important species in other comets, especially Halley's Comet, are explored.

Description: The C3H radical has been identified in the millimeter-wave spectra of IRC +10216 and TMC-1. In IRC +10216, four rotational transitions have been observed, three in the lower fine-structure ladder (2Pi1/2) and one in the upper (2Pi3/2), each a resolved or partially resolved lambda-doublet. In TMC-1, both lambda components of the lowest lying 3/2-1/2 transition of the 2Pi1/2 ladder have been observed, each with well-resolved hfs. In IRC +10216, the excitation of C3H is similar to that of SiCC: the rotational temperature Trot within the 2Pi1/2 ladder is low (8.5 K), because of rapid radiative decay, while Trot across the ladders is high (about 52 K), because interconnecting far-IR radiative transitions are only weakly permitted. The column density of C3H in IRC +10216 averaged over the estimated source diameter of 84 arcsec is 2.8 x 10 to the 13th/sq cm, an order of magnitude less than that of C2H and C4H.