ALBERT

Description: An Integrated Control and Health Monitoring (ICHM) system was conceived for use on a 20 Klb thrust baseline Orbit Transfer Vehicle (OTV) engine. Considered for space used, the ICHM was defined for reusability requirements for an OTV engine service free life of 20 missions, with 100 starts and a total engine operational time of 4 hours. Functions were derived by flowing down requirements from NASA guidelines, previous OTV engine or ICHM documents, and related contracts. The elements of an ICHM were identified and listed, and these elements were described in sufficient detail to allow estimation of their technology readiness levels. These elements were assessed in terms of technology readiness level, and supporting rationale for these assessments presented. The remaining cost for development of a minimal ICHM system to technology readiness level 6 was estimated. The estimates are within an accuracy range of minus/plus 20 percent. The cost estimates cover what is needed to prepare an ICHM system for use on a focussed testbed for an expander cycle engine, excluding support to the actual test firings.

Description: Solid-solution partitioning of Ra determines the dissolved Ra composition of porewater in marine sands. Therefore, sorption controls also influence the endmember concentration of Ra in submarine groundwater discharge (SGD). Ra is widely used as a tracer of SGD, and constraining sorption controls in permeable sands is necessary to evaluate spatial and temporal variation in Ra groundwater activities. This work presents Ra distribution coefficients measured in seawater (salinity 35) for some common solid sorbents as well as different solution compositions relevant to permeable marine sands and the subterranean estuary. There was a strong correlation of Ra distribution coefficient (Kd = solid-phase Ra/solution Ra) with surface area for size-fractionated sediments (log Kd (L/g) = 0.77 [log S.A. (m2/g)] + 0.73; r2 = 0.76). Ra sorption showed no direct relationship with solid-phase Fe or Mn content of the sands, although removal of visible surficial oxide coatings with dilute acid reduced Kd by a factor of 2 to 3. Synthetic Fe-oxides showed nearly two orders of magnitude difference in Ra sorption. Ferrihydrite had the highest Ra sorption coefficient at 1535 ± 410 L kg− 1, followed by lepidocrocite (174 ± 21 L kg− 1), hematite (75 ± 17 L kg− 1), and goethite (20 ± 8 L kg− 1). A marked increase in Ra adsorption was observed with increasing pH, with the sorption edge of natural sands falling within the pH range of 5–8. The extent of Ra sorption at a given pH varied among different substrates. No effect of dissolved Fe was observed on Ra partitioning. A large increase in Ra Kd was evident with increasing Ba concentration when seawater contained sulfate, opposite the effect that would be expected for sorption competition. No effect of Ba concentration was observed when sulfate was excluded from the ASW, indicating that barite precipitation caused the Kd increase. There was no clear effect of temperature on Ra sorption between 2 and 60 °C. Results of this study show that minor solid-phase components increase the Ra sorption capacity of bulk sands and buffer the dissolved Ra concentration (i.e., the SGD endmember). Solution controls on Ra sorption have the potential to greatly alter the Ra composition of discharging groundwater. Given that high-salinity, high-pH conditions probably prevail in porewater below the sediment–water interface, the actual SGD Ra endmember may be less variable than suggested by compilations that include groundwater from deep and fresh groundwater. Highlights ► Variable Ra partitioning to size-fractionated and diverse sediments was primarily controlled by specific surface area. ► Ra displayed pH-dependent sorption to sands, with a sorption edge between pH 5 and 8. ► No effect on Ra partitioning was observed for temperature or competition by dissolved Fe and Ba.