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  • 1
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    Semimetal clustering in intermetallic phases (1985)
    Elsevier
    Details
    Publication Date: 1985-03-01
    Print ISSN: 0022-4596
    Electronic ISSN: 1095-726X
    Topics: Chemistry and Pharmacology
    Published by Elsevier
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    PAPER CURRENT
  • 2
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    New SbS2 strings in the BaSb2S4 structure (1984)
    Elsevier
    Details
    Publication Date: 1984-08-01
    Print ISSN: 0022-4596
    Electronic ISSN: 1095-726X
    Topics: Chemistry and Pharmacology
    Published by Elsevier
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    PAPER CURRENT
  • 3
    Electronic Resource
    Electronic Resource
    Zur Kenntnis von Aluminiumthiophosphat AIPS4 (1960)
    Springer
    Naturwissenschaften 47 (1960), S. 495-495 
    Details
    ISSN: 1432-1904
    Source: Springer Online Journal Archives 1860-2000
    Topics: Biology , Chemistry and Pharmacology , Natural Sciences in General
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1007/BF00631053
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  • 4
    Electronic Resource
    Electronic Resource
    Zur Kenntnis von kubischem Aluminiumsulfid (1963)
    Weinheim : Wiley-Blackwell
    Zeitschrift für anorganische Chemie 325 (1963), S. 77-88 
    Details
    ISSN: 0044-2313
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Description / Table of Contents: A cubic, As-containing modification of Al2S3 has been prepared by reaction of Al + As + 4 S.Crystallographic data: cubic, a = 9.93 ± 0.01 Å; Fd3m - 07h; d20°C = 2.80 g/cm3, dx = 2.78 g/cm3.Atomic positions: 32 S atoms in 32e with x = 3/8; 16 Al-atoms in 16c; 5.33 Al atoms statistically in tetrahedral positions (8b).
    Notes: Versuche zur Darstellung von AlAsS4 lieferten statt der gesuchten Verbindung hexagonales Al2S3, wenn AlAs mit Schwefel umgesetzt wurde. Aus einem stöchiometrischen Gemenge von Al, As und 4 S dagegen bildete sich ein bisher unbekanntes, kubisches Al2S3. in dem etwa 2 Atom%% Al durch As ersetzt sind.Kristallographische Daten: Kubisch  -  Raumgruppe Fd3m  -  O7h; a = 9,93 ± 0,01 Å; d20°C = 2,80 g/cm3; dx = 2,78 g/cm3.Punktlagen: 32 Schwefelatome in 32e mit x = 3/8; 16 Aluminiumatome in Oktaederlücken (16c) bei 1/8 1/8 1/8 und 5,33 Aluminiumatome statistisch in Tetraederlücken (8b) bei 1/2 1/2 1/2.
    Additional Material: 3 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/zaac.19633250112
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  • 5
    Electronic Resource
    Electronic Resource
    Zur Kenntnis der Disilicide der Erdalkalimetalle (1970)
    Weinheim : Wiley-Blackwell
    Zeitschrift für anorganische Chemie 372 (1970), S. 87-99 
    Details
    ISSN: 0044-2313
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Description / Table of Contents: The crystal structures of BaSi2, SrSi2 and of a new modification of CaSi2 are described. The Si arrangements in these structures are discussed. There are Si4 tetrahedrons in BaSi2, a Sin threedimensional framework in SrSi2 and twodimensional corrugated sheets of Si hexagons in CaSi2.
    Notes: Die Kristallstrukturen von BaSi2 und SrSi2 werden beschrieben. Von CaSi2 wurde eine neue Modifikation aufgefunden. Die in den 3 Phasen nachgewiesenen Si-Verbände (Si4-Tetraeder im BaSi2, Sin-Raumnetzgerüst im SrSi2 und Sin-Schichten im CaSi2) werden vergleichend diskutiert.
    Additional Material: 6 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/zaac.19703720110
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  • 6
    Electronic Resource
    Electronic Resource
    Zur Kenntnis Ternärer Disilicide der Erdalkalimetalle (1970)
    Weinheim : Wiley-Blackwell
    Zeitschrift für anorganische Chemie 372 (1970), S. 325-331 
    Details
    ISSN: 0044-2313
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Description / Table of Contents: The ternary disilicides of group-II elements Ca1-xSrxSi2 und Sr1-xBaxSi2 are prepared and crystallographically investigated. In the quasibinary system CaSi2—SrSi2 the structures of the Ca-rich phases can be described as stacks of twodimensional corrugated sheets of Si hexagons. The phases Sr1-xBaxSi2 with X = 0.2 to X = 1.0 crystallize in the structure type of BaSi2 with isolated Si4 tetrahedrons. There in no miscibility between CaSi2 and BaSi2 in the solid phase.
    Notes: Die ternären Erdalkalidisilicide der Stöchiometrie Ca1-xSrxSi2 und Sr1-xBaxSi2 wurden dargestellt und röntgenographisch charakterisiert. Im quasibinären Schnitt CaSi2—SrSi2 wurden im Ca-reichen Teil Phasen erhalten, deren Strukturen sich als Stapelvarianten mit zweidimensionalen, gewellten Si-Sechsecknetzen erwiesen. Im System Sr1-xBaxSi2 tritt der Strukturtyp des BaSi2 mit isolierten Si4-Tetraedern von x = 0,2 bis x = 1,0 auf. Der quasibinäre Schnitt BaSi2—CaSi2 entspricht dem Zustandsdiagramm eines Zweistoffsystems ohne Mischkristallbildung.
    Additional Material: 4 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/zaac.19703720309
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  • 7
    Electronic Resource
    Electronic Resource
    Zur Strukturchemie der Verbindungsreihe BaMg2X2 (X = Si, Ge, Sn, Pb) (1974)
    Weinheim : Wiley-Blackwell
    Zeitschrift für anorganische Chemie 403 (1974), S. 163-172 
    Details
    ISSN: 0044-2313
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Description / Table of Contents: On the Structural Chemistry of BaMg2X2 (X = Si, Ge, sn, Pb)The new compounds BaMg2X2 (X = Si, Ge, Sn, Pb) have been prepared and their structures have been determined. BaMg2Si2 and BaMg2Ge2 crystallize in the ThCr2Si2-type, BaMg2Sn2 and BaMg2Pb2 show two new atomic arrangements, which are layer variants of the former type.
    Notes: Die Verbindungen BaMg2X2 (X = Si, Ge, Sn, Pb) wurden dargestellt und strukturell untersucht. BaMg2Si2 und BaMg2Ge2 kristallisieren im ThCr2Si2-Typ während BaMg2Sn2 und BaMg2Pb2 jeweils neue Strukturtypen ausbilden. Diese lassen sich aber als Schichtvarianten an den ThCr2Si2-Typ anschließen.
    Additional Material: 6 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/zaac.19744030210
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  • 8
    Electronic Resource
    Electronic Resource
    Darstellung und Kristallstruktur von KSbS2 (1975)
    Weinheim : Wiley-Blackwell
    Zeitschrift für anorganische Chemie 414 (1975), S. 211-219 
    Details
    ISSN: 0044-2313
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Description / Table of Contents: Preparation and Crystal Structure of KSbS2Red KSbS2 was prepared in a aqueous solution of KHS and Sb2S3 under mild hydrothermal conditions. For crystallographic data see „Inhaltsübersicht“. There are SbS2--chains, built up by ψ-trigonal bipyramids, which are connected by sharing edges. The K+-Ions between these chains have a nearly octaedric coordination.
    Notes: Rotes KSbS2 wurde aus wässerigen Lösungen von KHS und Sb2S3 unter milden hydrothermalen Bedingungen dargestellt und strukturell untersucht. Die kristallographischen Daten sind: monoklin, Raumgruppe C2/c—C2h6 a = 8,75 ± 0,01 Å, b = 8,98 ± 0,01 Å, c = 6,84 ± 0,01 Å β = 121,6° ± 0,1 4 Formeleinheiten in der Elementarzelle. Nach der vollständigen röntgenographischen Strukturaufklärung liegen SbS2--Kettenanionen vor, die aus über Kanten verknüpften ψ-trigonalen Bipyramiden aufgebaut sind. Zwischen diesen Ketten sitzen die Kaliumionen mit einer nahezu oktaedrischen Koordination.
    Additional Material: 5 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/zaac.19754140304
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  • 9
    Electronic Resource
    Electronic Resource
    Darstellung und Kristallstruktur von (NH4)2Sb4S7 (1977)
    Weinheim : Wiley-Blackwell
    Zeitschrift für anorganische Chemie 437 (1977), S. 183-187 
    Details
    ISSN: 0044-2313
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Description / Table of Contents: Preparation and Crystal Structure of (NH4)2Sb4S7(NH4)2Sb4S7 has been prepared and its structure determined. It crystallizes orthorhombic, space group Pbca, with \documentclass{article}\pagestyle{empty}\begin{document}$$ {\rm a = 1 133}{\rm .0(3) pm, b = 2625}{\rm .2(6) pm, c = 994}{\rm .0(3) pm}{\rm .} $$\end{document} Three distorted trigonal SbS3-pyramids are connected to a Sb3S3-ring in chair-conformation. These rings are bridged by further SbS3-pyramids to infinite chiralic chains.
    Notes: (NH4)2Sb4S7 wurde dargestellt und strukturell aufgeklärt. Es kristallisiert orthorhombisch, Raumgruppe Pbca, mit \documentclass{article}\pagestyle{empty}\begin{document}$$ {\rm a = 1 133,0(3) pm, b = 2625,2(6) pm, c = 994,0(3) pm}{\rm .} $$\end{document} Im Anionengitter sind jeweils 3 verzerrte trigonale SbS3-Pyramiden zu Sb3S3-Sechsringen in Sesselkonformation verknüpft. Diese Ringe sind über weitere SbS3-Pyramiden zu eindimensional unendlichen gewundenen Ketten verbunden.
    Additional Material: 3 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/zaac.19774370125
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  • 10
    Electronic Resource
    Electronic Resource
    Darstellung und Kristallstruktur von Cs2Sb4S7 (1978)
    Weinheim : Wiley-Blackwell
    Zeitschrift für anorganische Chemie 441 (1978), S. 98-102 
    Details
    ISSN: 0044-2313
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Description / Table of Contents: Preparation and Crystal Structure of Cs2Sb4S7The first thioantimonite of Cesium has been synthesized and its crystal structure determined. The substance crystallizes monoclinic with spacegroup P21/c. The lattice constants are a = 1111.2(5) pm, b = 1227.1(5) pm, c = 1163.7(5) pm and ß = 97.60(5)°. There are four formula units in the unit cell. Sb-S chains are formed by trigonal SbS3 pyramids and ψ-trigonal SbS4 bipyramids.
    Notes: Als erstes Cäsiumthioantimonit wurde die Verbindung Cs2Sb4S7 aus wäßriger Sulfidlösung dargestellt und ihre Kristallstruktur aufgeklärt. Sie kristallisiert monoklin in der Raumgruppe P21/c mit den Gitterkonstanten: a = 1111,2(5) pm. b = 1227,1(5) pm, c = 1163,7(5) pm, ß = 97,60(5)°. Die Elementarzelle enthält 4 Formeleinheiten. Es liegen Sb-S-Kettenverbände vor, die aus trigonalen SbS3-Pyramiden und ψ-trigonalen SbS4-Bipyramiden gebildet werden.
    Additional Material: 2 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/zaac.19784410112
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