ALBERT

Description: Volatile species such as H2O, CO2, F, and Cl have significant impact in generation and differentiation of basaltic melts. Thus far experimental work has primarily focused on the effect of water and carbon dioxide on basalt crystallization, liquid-line of descent, and mantle melting [e.g., 1, 2] and the effects of halogens have received far less attention [3-4]. However, melts in the planetary interiors can have non-negligible chlorine and fluorine concentrations. Here, we explore the effects of fluorine on near-liquidus phase equilibria of basalt. We have conducted nominally anhydrous piston cylinder experiments using graphite capsules at 0.6 - 1.5 GPa on an Fe-rich model basalt composition. 1.75 wt% fluorine was added to the starting mix in the form of AgF2. Fluorine in the experimental glass was measured by SIMS and major elements of glass and minerals were analyzed by EPMA. Nominally volatile free experiments yield a liquidus temperature from 1330 C at 0.8GPa to 1400 at 1.6GPa and an olivine(Fo72)-pyroxene(En68)-liquid multiple saturation point at 1.25 GPa and 1375 C. The F-bearing experiments yield a liquiudus temperature from 1260 C at 0.6GPa to 1305 at 1.5GPa and an ol(Fo66)-pyx(En64)-MSP at 1 GPa and 1260 C. This shows that F depresses the basalt liquidus, extends the pyroxene stability field to lower pressure, and forces the liquidus phases to be more Fe-rich. KD(Fe-Mg/mineral-melt) calculated for both pyroxenes and olivines show an increase with increasing F content of the melt. Therefore, we infer that F complexes with Mg in the melt and thus increases the melt s silica activity, depressing the liquidus and changing the composition of the crystallizing minerals. Our study demonstrates that on a weight percent basis, the effect of fluorine is similar to the effect of H2O [1] and Cl [3] on freezing point depression of basalts. But on an atomic fraction basis, the effect of F on liquidus depression of basalts is xxxx compared to the effect of H. Future studies on kimberlitic and subduction zone magmas, which could have significant amount of fluorine, will need to consider the combined effects of F, Cl, and H on their stability and chemical evolution.

Description: The solubility of H2O in silicate melt drops substantially with decreasing pressure, so that a magma initially containing several weight percent H2O in a crustal magma reservoir is left with only a few thousand parts per million following ascent and eruption at the Earth’s surface. This rapid release of volatiles makes determining the pre-eruptive H2O contents of magmas very difficult. Olivine-hosted melt inclusions are thought to retain their H2O because they are protected from decompression by the strength of the host crystal, and pre-eruptive concentrations obtained from melt inclusions have been used to both estimate the amount of H2O in the upper mantle and investigate its role in the melt generation process. The greatest uncertainty involved in constraining upper mantle conditions from melt inclusions is the potential for rapid diffusive loss or gain of H+ (protons) through the host olivine. Here we present results from hydration and dehydration experiments that demonstrate that, contrary to the widely held view, H2O loss or gain in melt inclusions is not limited by redox reactions and significant fluxes of H+ through the host olivine are possible on very short time scales. We also show that the Fe3+/ΣFe of an olivine-hosted melt inclusion maintains equilibrium with the external environment via diffusion of point defects through the host olivine. Our results demonstrate that, while pre-eruptive H2O and Fe3+/ΣFe can be reliably estimated, olivine-hosted melt inclusions do not necessarily retain a record of the H2O and O2 fugacity conditions at which they formed. High-H2O melt inclusions are particularly susceptible to diffusive dehydration, and therefore are not reliable proxies for the state of the upper mantle.

Description: A systematic study of rare earth and other trace elements in discrete diopsides from residual abyssal peridotites sampled from 5000 km of ocean ridge demonstrates that they are the residues of variable degrees of melting in the garnet and spinel peridotite fields. Further, the data clearly demonstrate that the peridotites are the residues of near‐fractional melting, not batch melting, and that typical abyssal basalt can evolve from aggregated fractional melts. Ion microprobe analyses of diopsides in abyssal peridotites from fracture zones along the America‐Antarctica and Southwest Indian ridges reveal ubiquitous extreme fractionation of rare earth elements (REE) ([Ce/Yb]n = 0.002–0.05); depletion of Ti (300–1600 ppm), Zr (0.1–10 ppm), and Sr (0.1–10 ppm); and fractionation of Zr relative to Ti (Ti/Zr = 250–4000). Ti and Zr in diopsides decrease with decreasing modal cpx in the peridotites, and samples dredged near hotspots are more depleted in incompatible elements than those dredged away from hotspots, consistent with higher degrees upper mantle melting in the former. All studied samples exhibit marked negative anomalies in Ti and Zr relative to REE. Incompatible element concentrations in peridotite clinopyroxenes are well modeled by repeated melting and segregation in ≤0.1% increments to a total of 5–25% melting, a process very close to Rayleigh (fractional) melting; batch melting of a LREE‐depleted source cannot account for the observed trace element concentrations in abyssal peridotites. The shapes of some REE patterns are consistent with variable degrees of melting initiated within the garnet stability field. Trace element concentrations in calculated integrated fractional liquids approximate the composition of primitive ocean floor basalts, consistent with postsegregation aggregation of small increment melts produced over a depth and melting interval.