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  • 1
    ISSN: 1573-0662
    Keywords: Hydrogen fluoride ; atmospheric composition ; trace gases ; trends
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology , Geosciences
    Notes: Abstract The amount of hydrogen fluoride (HF) above the International Scientific Station of the Jungfraujoch (Switzerland) has been monitored during the last 8 years. The results deduced spectro-scopically from solar IR absorption measurements near 2.48 μm indicate a cumulative trend equivalent to (8.5±1)% increase per year, as well as short-term variability which appears to be strongly correlated with meridional circulation patterns during the February–April months. Based on intensified measurements made over the last three years, it is found that the integrated content of HF undergoes a seasonal change with a minimum occurring in the fall. The HF/HCl ratio derived from simultaneous HF and HCl measurements was found equal to 0.15 during the period 1977–79, and 0.24 for the 1983–85 timespan.
    Type of Medium: Electronic Resource
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  • 2
    ISSN: 1573-0662
    Keywords: Hydrogen chloride ; atmospheric composition ; trace gases ; trends
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology , Geosciences
    Notes: Abstract The integrated column amount of hydrogen chloride has been monitored above the International Scientific Station of the Jungfraujoch (Switzerland) during the last 8 years. The results deduced from solar absorption measurements near 3.42 μm indicate a secular trend equivalent to (0.75±0.2) % increase per year since 1978, superimposed on a significant short-term variability which can be partly attributed to the tropospheric component of the total HCl burden. Based on an intensified set of measurements carried out over the last three years, a seasonal component in the total content of HCl has been established for the first time, showing a minimum occuring in early winter and a maximum during the spring.
    Type of Medium: Electronic Resource
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