ISSN:
1572-8943
Keywords:
empirical equations
;
excess enthalpy
;
group contribution
;
ternary mixtures
Source:
Springer Online Journal Archives 1860-2000
Topics:
Chemistry and Pharmacology
Notes:
Abstract Studies were previously made of the excess molar enthalpies, Hm E, at 298.15 K and normal atmospheric pressure of the ternary mixtures (ethyl propanoate or 3-pentanone) + (n-hexane) + (n-decane, n-dodecane or n-tetradecane) and (1-propanol) + (3-pentanone) + (n-hexane, n-heptane, n-octane, 1-hexanol or 1-heptanol). In the present work, experimental values of Hm E were correlated through use of the Cibulka and Nagata equations, and a new correlation equation is proposed. Experimental data were compared with the predictions of the UNIFAC I (version of Tassios), UNIFAC II (version of Larsen) and Nitta-Chao group contribution models. Hm E values were used to test several empirical predictive methods, both symmetric (Kohler, Jacob-Fitzner, Colinet and Knobeloch-Schwartz), and asymmetric (Tsao-Smith, Toop, Scatchard, Hillert and Mathieson-Tynne).
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1023/A:1010170825253
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