ISSN:
1572-9028
Keywords:
metal-organic
;
microporous
;
frameworks
;
sorption
;
isotherm
Source:
Springer Online Journal Archives 1860-2000
Topics:
Chemistry and Pharmacology
Notes:
Abstract Metal-carboxylate clusters are ideally suited as secondary building units (SBU) for the assembly of extended open frameworks. Examples extracted from the chemistry of the multidentate building block 1,4-benzenedicarboxylate (BDC) show that Zn(BDC) clusters lead to the formation of rigid, stable and truly microporous metal-carboxylate networks. Gas sorption isotherms measured for this class of materials show type (I) gas uptake that is analogous to those observed for zeolites and molecular sieves.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1023/A:1019110622091
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