ISSN:
1435-1536
Schlagwort(e):
Poly(pentafluorostyrene)
;
excimer emission
;
repulsive Coulombic interactions
;
singlet excimer
;
sandwich conformation
Quelle:
Springer Online Journal Archives 1860-2000
Thema:
Chemie und Pharmazie
,
Maschinenbau
Notizen:
Abstract The steady-state fluorescence emission spectrum of poly(pentafluorostyrene) in dilute fluid solution shows no excimer emission. An atomic level modeling study explains why this polymer cannot form an excimer. Repulsive Coulombic interactions prohibit the attainment of the extensive overlap of the two rings in the classic face-to-face sandwich conformation of a singlet excimer.
Materialart:
Digitale Medien
URL:
http://dx.doi.org/10.1007/BF00657447
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