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  • 1
    Electronic Resource
    Electronic Resource
    Springer
    Journal of statistical physics 49 (1987), S. 1053-1081 
    ISSN: 1572-9613
    Keywords: Percolation ; phase separation ; Monte Carlo simulation ; lattice gas model ; finite-size scaling
    Source: Springer Online Journal Archives 1860-2000
    Topics: Physics
    Notes: Abstract The percolation transition of geometric clusters in the three-dimensional, simple cubic, nearest neighbor Ising lattice gas model is investigated in the temperature and concentration region inside the coexistence curve. We consider “quenching experiments,” where the system starts from an initially completely random configuration (corresponding to equilibrium at infinite temperature), letting the system evolve at the considered temperature according to the Kawasaki “spinexchange” dynamics. Analyzing the distributionn l(t) of clusters of sizel at timet, we find that after a time of the order of about 100 Monte Carlo steps per site a percolation transition occurs at a concentration distinctly lower than the percolation concentration of the initial random state. This dynamic percolation transition is analyzed with finite-size scaling methods. While at zero temperature, where the system settles down at a frozen-in cluster distribution and further phase separation stops, the critical exponents associated with this percolation transition are consistent with the universality class of random percolation, the critical behavior of the transient time-dependent percolation occurring at nonzero temperature possibly belongs to a different, new universality class.
    Type of Medium: Electronic Resource
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  • 2
    Electronic Resource
    Electronic Resource
    Springer
    Journal of statistical physics 80 (1995), S. 1009-1031 
    ISSN: 1572-9613
    Keywords: Monte Carlo simulation ; thin films of symmetrical polymer mixtures ; phase separation ; crossover scaling ; critical temperature ; phase diagram in the thermodynamic limit
    Source: Springer Online Journal Archives 1860-2000
    Topics: Physics
    Notes: Abstract Monte Carlo simulations of the bond fluctuation model of symmetrical polymer blends confined between two “neutral” repulsive walls are presented for chain lengthN A=N B=32 and a wide range of film thicknessD (fromD=8 toD=48 in units of the lattice spacing). The critical temperaturesT c (D) of unmixing are located by finite-size scaling methods, and it is shown that $$T_c (\infty ) - T_c (D) \propto D^{ - {1 \mathord{\left/ {\vphantom {1 {v_3 }}} \right. \kern-\nulldelimiterspace} {v_3 }}} $$ , wherev 3≈0.63 is the correlation length exponent of the three-dimensional Ising model universality class. Contrary to this result, it is argued that the critical behavior of the films is ruled by two-dimensional exponents, e.g., the coexistence curve (difference in volume fraction of A-rich and A-poor phases) scales as $$\phi _{cocx}^{(2)} - \phi _{cocx}^{(1)} = \hat B(D)\left[ {1 - {T \mathord{\left/ {\vphantom {T T}} \right. \kern-\nulldelimiterspace} T}_c (D)} \right]^{\beta _2 } $$ , whereβ 2 is the critical exponent of the two-dimensional Ising universality class (β 2=1/8). Since for largeD this asymptotic critical behavior is confined to an extremely narrow vicinity ofT c (D), one observes in practice “effective” exponents which gradually cross over fromβ 2 toβ 3 with increasing film thickness. This anomalous “flattening” of the coexistence curve should be observable experimentally.
    Type of Medium: Electronic Resource
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