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  • partially acidulated phosphate rock  (7)
  • phosphorus availability  (3)
  • 1
    ISSN: 1573-0867
    Schlagwort(e): phosphate rock ; partially acidulated phosphate rock ; iron and aluminium oxide content ; water and citrate solubility ; phosphorus availability ; agronomic effetiveness
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Land- und Forstwirtschaft, Gartenbau, Fischereiwirtschaft, Hauswirtschaft
    Notizen: Abstract Partially acidulated phosphate rock (PAPR) has been shown to be an effective source of P for plants grown on acid soils. Less information in available, however, regarding the effect of the phosphate rock (PR) source on the solubility and agronomic effectiveness of PAPR. The effect of Fe2O3 + Al2O3 content in PR on the quality of PAPR produced was investigated in this study. Nine sources of PR from Africa, Latin America, and the United States, representing a range of Fe2O3 + Al2O3 from 0.7% to 12.4%, were used. In a single-step process, the finely ground PRs were partially acidulated with H2SO4 at the 30% or 50% acidulation level and granulated (−3.35 + 1.18 mm or −6 + 14 mesh). It was found that the water-soluble P content in PAPR decreased with increasing Fe2O3 + Al2O content in the PR used. Apparently, the presence of Fe2O3 + Al2O3 resulted in a reversion of some of the water-soluble P to citrate-soluble P and sometimes even to citrate-insoluble P. A short-term (6 weeks) greenhouse study was conducted to evaluate crop response to PAPRs and single superphosphate (SSP); maize, the test crop, was grown on an acid soil (pH 4.5)—Hartsells silt loam (Typic Hapludults). The agronomic effectiveness of PAPRs with respect to SSP (in terms of dry-matter yield of maize) decreased with increasing Fe2O3 + Al2O3 content in PRs. Phosphorus uptake by maize from PAPRs was found to correlate well with water solubility but not with citrate solubility. The results obtained in this study show that the detrimental effect of Fe2O3 + Al2O3 content on the solubility and P availability of PAPR should be considered when selecting a PR for PAPR production.
    Materialart: Digitale Medien
    Standort Signatur Erwartet Verfügbarkeit
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  • 2
    ISSN: 1573-0867
    Schlagwort(e): Pi soil test ; Olsen test ; calcareous soils ; partially acidulated phosphate rock ; soil test correlation
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Land- und Forstwirtschaft, Gartenbau, Fischereiwirtschaft, Hauswirtschaft
    Notizen: Abstract The Pi test for phosphorus (P) is a new method in which strips of iron oxide impregnated filter paper are used as a sink to sorb and extract P from a soil solution. In a greenhouse experiment, the Olsen and Pi tests were compared for their effectiveness in evaluating P availability to maize on calcareous soils. Phosphate rock from Togo, partially acidulated with H2SO4 at 50% acidulation level (PAPR 50% H2SO4) and single superphosphate (SSP) were applied at different rates to a calcareous soil (Vernon Clay, pH 8.2, CaCO3 18.9%) which was preincubated with KH2PO4 to raise plant-available P to different levels. In soils treated with SSP, dry-matter yield of maize correlated equally well with Pi-P and with Olsen-P (r = 0.96***). P uptake correlated significantly with Pi-P (r = 0.94***) as well as Olsen-P (r = 0.97***). Likewise, in soils fertilized with PAPR, significant correlations were found between dry-matter yield and Pi-P (r = 0.97***) and between dry-matter yield and Olsen-P (r = 0.94***). When all the data were pooled, Pi-P and Olsen-P correlated equally well with both dry-matter weight (r = 0.97***) and P uptake (r = 0.94***). Phosphorus extracted by the Pi test correlated significantly with P extracted by the Olsen test (r = 0.99***).
    Materialart: Digitale Medien
    Standort Signatur Erwartet Verfügbarkeit
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  • 3
    Digitale Medien
    Digitale Medien
    Springer
    Nutrient cycling in agroecosystems 41 (1995), S. 197-209 
    ISSN: 1573-0867
    Schlagwort(e): agronomic effectiveness ; compacted phosphate rock with superphosphate ; partially acidulated phosphate rock
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Land- und Forstwirtschaft, Gartenbau, Fischereiwirtschaft, Hauswirtschaft
    Notizen: Abstract Phosphorus (P) is critically needed to improve the soil fertility for crop production in large areas of developing countries. The high cost of conventional, water-soluble P fertilizers constrains their use by resource-poor farmers. Finely ground phosphate rock (PR) has been tested and used as a direct application fertilizer on tropical acid soils as a low-cost alternative where indigenous deposits of PR are located. However, direct application of PR with low reactivity or with inappropriate soil/crop combinations does not always give satisfactory results. Partial acidulation of PR (PAPR) or compaction with triple superphosphate (PR + TSP) or single superphosphate (PR + SSP) represent technologies that can be used to produce highly effective P fertilizers from those indigenous deposits. Numerous field trials conducted by IFDC in Asia, sub-Saharan Africa, and Latin America have demonstrated that PAPR at 40-50% acidulation with H2SO4 or at 20% with H3PO4 approaches the effectiveness of SSP or TSP in certain tropical soils and crops. This paper discusses how the agronomic effectiveness of PAPR is affected by mineralogical composition and reactivity of PR used and by soil properties and soil reactions. The paper also indicates that if a PR has high Fe2O3 + Al2O3 content, it may not be suitable for PAPR processing because of the reversion of water-soluble P to water-insoluble P during the PAPR manufacturing process. Under these conditions, compaction of PR with water-soluble P fertilizers (e.g. SSP, TSP) at P ratio of approximately 50:50 can be agronomically and economically attractive for utilizing the indigenous PRs in developing countries.
    Materialart: Digitale Medien
    Standort Signatur Erwartet Verfügbarkeit
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  • 4
    Digitale Medien
    Digitale Medien
    Springer
    Nutrient cycling in agroecosystems 44 (1995), S. 113-122 
    ISSN: 1573-0867
    Schlagwort(e): Compacted phosphate rock ; partially acidulated phosphate rock ; phosphate rock ; relative effectiveness ; TSP
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Land- und Forstwirtschaft, Gartenbau, Fischereiwirtschaft, Hauswirtschaft
    Notizen: Abstract Partial acidulation of phosphate rock (PR) or compaction of PR with soluble P fertilizers can improve the usefulness of unreactive PR for use as P fertilizer. A greenhouse study was conducted to evaluate nonconventional phosphate fertilizers derived from a low reactive Sukulu Hills PR from Uganda. Raw PR (which contained 341.0 g kg−1 Fe2O3), beneficiated or concentrate PR, partially acidulated PR (PAPR) and PR compacted with triple superphosphate (TSP) were evaluated. Compacted materials had a P ratio of PR:TSP = 50:50. PAPR materials were made by 50% acidulation with H2SO4. TSP was used as a reference fertilizer. Fertilizers were applied to an acidic (pH = 5.4) Hiwassee loam (clayey, kaolinitic, thermic Rhodic Kanhapludults) at rates of 0, 50, 100, 200, 300 and 400 mg P kg−1 soil. Two successive corn (Zea mays L.) crops were grown for 6 weeks. Compacted concentrate PR + TSP and raw PR + TSP were 94.4 and 89.7% as effective as TSP, respectively, in increasing dry-matter yields for the first corn crop. PAPR from the concentrate was 54.8% as effective as TSP. Raw PR, concentrate PR and the PAPR from the raw PR were ineffective in increasing dry-matter yields. The same trends were obtained when P uptake was used to compare effectiveness. Ineffectiveness of the raw PR and its corresponding PAPR was attributed to a high Fe2O3 content in the raw PR. Bray I and Pi paper were found to be nearly equally suitable at estimating available P in the soils treated with responsive fertilizer materials. Mehlich 1 overestimated available P in soil treated with raw PR, concentrate PR or the PAPR from the raw PR.
    Materialart: Digitale Medien
    Standort Signatur Erwartet Verfügbarkeit
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  • 5
    Digitale Medien
    Digitale Medien
    Springer
    Nutrient cycling in agroecosystems 44 (1995), S. 231-240 
    ISSN: 1573-0867
    Schlagwort(e): compacted phosphate rock ; partially acidulated phosphate rock ; P availability ; phosphate rock ; P fixation capacity ; relative effectiveness
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Land- und Forstwirtschaft, Gartenbau, Fischereiwirtschaft, Hauswirtschaft
    Notizen: Abstract A greenhouse study was conducted with two surface, acidic soils (a Hiwassee loam and a Marvyn loamy sand) to measure the effect of increasing P-fixation capacity, on the relative agronomic effectiveness (RAE) of phosphate fertilizers derived from Sukulu Hills phosphate rock (PR) from Uganda. Prior to fertilizer application, Fe-gel was added to increase P-fixation capacity from 4.4 to 14.3% for the Marvyn soil and from 37.0 to 61.5% for the Hiwassee soil. Phosphate materials included compacted Sukulu Hills concentrate PR + Triple superphosphate (CTSP) at a total P ratio of PR:TSP = 50:50; 50% partially acidulated PR (CPAPR) from Sukulu Hills concentrate PR made with H2SO4; and Sukulu Hills concentrate PR (PRC) made by magnetically removing iron oxide from raw PR ore. Triple superphosphate (TSP) was used as a reference fertilizer. After adjusting soil pH to approximately 6, P sources were applied at rates of 0, 50, 150, and 300 mg total P kg−1 soil. Two successive crops of 5 week old corn seedlings (Zea mays L.) were grown. The results show that the RAE of the phosphate materials measured using dry-matter yield or P uptake generally decreased as P-fixation capacity was increased for both soils. CTSP was more effective in increasing dry-matter yield and P uptake than CPAPR. PRC alone was an ineffective P source. Soil chemical analysis showed that Bray 1 and Mehlich 1 extractants were ineffective on the high P-fixation capacity Fe-gel amended Hiwassee soil. Mehlich 1 was unsuitable for soils treated with PRC since it apparently solubilizes unreactive PR. When all of the soils and P sources were considered together, Pi paper was the most reliable test for estimating plant available P.
    Materialart: Digitale Medien
    Standort Signatur Erwartet Verfügbarkeit
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  • 6
    Digitale Medien
    Digitale Medien
    Springer
    Nutrient cycling in agroecosystems 1 (1980), S. 37-49 
    ISSN: 1573-0867
    Schlagwort(e): phosphate rock ; degrees of acidulation ; phosphorus availability ; granule size ; water-soluble P ; citrate-soluble P ; agronomic effectiveness
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Land- und Forstwirtschaft, Gartenbau, Fischereiwirtschaft, Hauswirtschaft
    Notizen: Abstract Two phosphate rocks, one from Pesca (Colombia) and the other from Togo, were acidulated to various degrees with H2SO4 and H3PO4 for evaluation in varying granule size ranges. Products acidulated with H2SO4 were also prepared using different drying temperatures. Phosphorus availability was measured by dry-matter yield and P uptake in greenhouse experiments with maize. It was observed that partial acidulation with H2SO4 was effective in increasing the water-soluble P level of phosphate rock when the drying temperature of the product was not excessive. Crop response and P uptake were both highly correlated to the water solubility of the product. The relative agronomic effectiveness (RAE) of Togo rock increased from 3% when unacidulated to 33%, 47%, and 52% when 20%, 30%, and 40%, respectively, of the H2SO4 required to make SSP was added. Similar results were obtained with Pesca rock. No consistent effect due to granule size was observed. Twenty percent acidulation of Pesca rock with H3PO4 was 53–76% as effective as TSP with a single crop and 79–90% as effective over three cropping periods, showing a potential for high residual value.
    Materialart: Digitale Medien
    Standort Signatur Erwartet Verfügbarkeit
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  • 7
    ISSN: 1573-5036
    Schlagwort(e): Bray I soil P test ; partially acidulated phosphate rock ; phosphate rock ; Pi soil P test
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Land- und Forstwirtschaft, Gartenbau, Fischereiwirtschaft, Hauswirtschaft
    Notizen: Abstract Phosphate rocks from seven locations in Africa and Latin America were partially acidulated with H2SO4 at 30% or 50% acidulation level and were applied to an acid silt loam. Dry-matter yield of and P uptake by maize grown on the soil were correlated with P measured by Bray I soil test and Pi soil test in which P is extracted by shaking a soil sample with 0.01M CaCl2 solution and a strip of iron hydroxide impregnated filter paper. There was a highly significant correlation between water-soluble P in the partially acidulated phosphate rocks (PAPR) and P measured by the Pi test (r=0.92**). The dry-matter yield correlated significantly with P measured by the Pi test (r=0.91**) as well as by the Bray test (r=0.73**). Phosphorus uptake correlated highly significantly with Pi−P (r=0.94**); correlation with Bray I−P was less significant (r=0.67*). Bray I solution extracted more P than Pi did, which resulted in an overestimation of plant-available P. Bray I therefore was less effective than the Pi soil test in evaluating P availability from different PAPRs applied to the soil.
    Materialart: Digitale Medien
    Standort Signatur Erwartet Verfügbarkeit
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  • 8
    ISSN: 1573-0867
    Schlagwort(e): phosphorus availability ; compacted phosphate rocks ; urea hydrolysis ; agronomic effectiveness
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Land- und Forstwirtschaft, Gartenbau, Fischereiwirtschaft, Hauswirtschaft
    Notizen: Abstract The possible effect of urea hydrolysis on the availability of phosphorus (P) from phosphate rock (PR) was evaluated in two greenhouse experiments with maize, using two sources of PR — Pesca (Colombia) and Bayovar (Peru) — representing low and high chemical reactivity, respectively. In Experiment I, on a neutral Josephine silty clay loam (pH 6.2) (Typic Haplozerult), Bayovar PR compacted with urea (Bayovar PR + urea) performed better than Bayovar PR compacted with NH4Cl (Bayovar PR + NH4Cl) in increasing dry-matter yield at a rate of 100 mg P kg−1 but not at rates of 50 and 200 mg P kg−1. It was also found that the dry-matter yield obtained with compacted Bayovar PR products was significantly higher when the N ratios of urea: NH4Cl were 1:1 or higher than when the ratios were below 1:1. Although Bray I–P can overestimate available P from PR with respect to that from TSP, a good relationship was observed between Bray I–P and dry-matter yield from various compacted Bayover PR products with a small particle size (−0.43 + 0.15 mm). In Experiment II an acid Bladen sandy loam (pH 4.5) (Typic Albaquult) was used. Finely ground Bayovar PR (− 0.07 mm) was about 66% as effective as TSP in increasing dry-matter yield, whereas Pesca PR was ineffective. When Pesca PR was partially acidulated with H3PO4 at 20% level (PAPR), it became 70% as effective as TSP. Granulated PAPR and Pesca PR compacted with TSP (Pesca PR + TSP) were found to be equally effective in increasing dry-matter yield when both products had the same particle size and the same water-soluble and citrate-soluble P as percent of total P, and when prilled urea was used as the N source. However, when urea was compacted with Pesca PR and TSP, the product's effectiveness was further increased by 30% and to the same level as TSP. In summary, the results tend to support the suggestion that urea hydrolysis can be beneficial in increasing the availability of P from PR to plants in soils having medium to high organic matter contents.
    Materialart: Digitale Medien
    Standort Signatur Erwartet Verfügbarkeit
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  • 9
    Digitale Medien
    Digitale Medien
    Springer
    Nutrient cycling in agroecosystems 24 (1990), S. 149-157 
    ISSN: 1573-0867
    Schlagwort(e): Phosphate rock ; SSP ; TSP ; partially acidulated phosphate rock ; relative effectiveness (RE) index ; substitution rate (SR)
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Land- und Forstwirtschaft, Gartenbau, Fischereiwirtschaft, Hauswirtschaft
    Notizen: Abstract Because various phosphate (P) fertilizers differ widely in their solubility, it is commonly observed that crop response to P fertilizers varies under the same soil and crop conditions. Furthermore, a major problem encountered in the methods for determining the relative effectiveness (RE) of water-insoluble P fertilizer (e.g., phosphate rock) with respect to water-soluble P fertilizers, e.g., single superphosphate (SSP) and triple superphosphate (TSP), is that their growth response curves are usually nonlinear and often do not share a common maximum yield. In this paper, we review and discuss the advantages and disadvantages of the three most commonly used methods for calculating the RE of phosphate rock with respect to TSP (or SSP). The three methods are vertical comparison, horizontal (substitution rate) comparison, and linear-response comparison.
    Materialart: Digitale Medien
    Standort Signatur Erwartet Verfügbarkeit
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