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Mechanical properties and molecular mobility in oriented polyolefines (1987)

Krisyuk, B. E. ; Popov, A. A. ; Zaikov, G. E. ; [et al.]

Springer

Colloid & polymer science 265 (1987), S. 220-225

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ISSN: 1435-1536

Keywords: Fibers ; elastic modulus ; correlation time ; molecularmobility ; orientation

Source: Springer Online Journal Archives 1860-2000

Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics

Notes: Abstract The static modulus of elasticity (E) and the correlation time of rotation (τ c ) of 2,-2,6,6-tetramethylpiperidine-1-oxyl are studied as a function of the temperature (210〈T 〈350°K) for oriented films of isotactic polypropylene and polyethylene of high and low density.E andτ c change both upon heating and polymer orientation; this result indicates that sample properties are influenced by the microstructure of the amorphous phase where probes are localized.

Type of Medium: Electronic Resource

URL: http://dx.doi.org/10.1007/BF01412710

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