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  • 1
    Electronic Resource
    Electronic Resource
    Olefins polymerization on titania and titania-supported rhodium (1991)
    Springer
    Catalysis letters 8 (1991), S. 37-43 
    Details
    ISSN: 1572-879X
    Keywords: Olefins polymerization ; Rh/TiO2 catalysts ; titania ; rhodium
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology
    Notes: Abstract The adsorption of ethene and propene on titania and titania-supported rhodium has been studied, observing a continuous adsorption even after 24 h. The samples have been reduced at 623 or 773 K, but no difference was observed, whichever the reduction temperature or the presence of rhodium, on the amount of gas adsorbed per unit of surface area of the solid. A study of the polymerization has been done following the “equal reactivity hypothesis”, and it has been concluded that the role played by the rhodium particles is to facilitate adsorption of the gaseous molecule, that is then transfered to the surface of the support, where it polymerizes.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1007/BF00764381
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  • 2
    Electronic Resource
    Electronic Resource
    New route for the synthesis of V2O5-MgO oxidative dehydrogenation catalysts (1987)
    Springer
    Journal of materials science 6 (1987), S. 616-619 
    Details
    ISSN: 1573-4811
    Source: Springer Online Journal Archives 1860-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1007/BF01739301
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  • 3
    Electronic Resource
    Electronic Resource
    Surface texture properties of TiO2 (rutile) pigments (1995)
    Springer
    Journal of materials science 14 (1995), S. 991-993 
    Details
    ISSN: 1573-4811
    Source: Springer Online Journal Archives 1860-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1007/BF00274628
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  • 4
    Electronic Resource
    Electronic Resource
    Hydrogenolysis of light hydrocarbons on Rh/TiO2. Catalysts reduced at high temperature (1986)
    Springer
    Reaction kinetics and catalysis letters 32 (1986), S. 215-219 
    Details
    ISSN: 1588-2837
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology
    Description / Table of Contents: Abstract Гидрогенолиз углеводородов состава C2 до C4 исследован на Rh/TiO2 (2,5 вес .% Rh), восстановленном в H2 при 773 К. Активность катализатора в этой реакции наблюдалась выше 480 К, приводя к образованию более низких углеводородов с увеличением температуры реакции.
    Notes: Abstract Hydrogenolysis of C2 to C4 hydrocarbons has been studied on Rh/TiO2 (2.5wt. % Rh) reduced in H2 at 773 K. Activity for this reaction is observed above 480 K, leading to lower hydrocarbons as the reaction temperature is increased.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1007/BF02063475
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  • 5
    Electronic Resource
    Electronic Resource
    Hydrogenolysis of n-butane on low-loaded Rh/TiO2, I. Catalysts obtained by ion exchange (1992)
    Springer
    Reaction kinetics and catalysis letters 47 (1992), S. 227-231 
    Details
    ISSN: 1588-2837
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology
    Description / Table of Contents: Abstract Описывают активность катализатора Rh/TiO2 (0,6 вес.% Rh), приготовленного ионным обменом и восстановленного при различных скоростях нагрева, в гидрогенолизе н-бутана. Скорость нагрева не влияет на свойства катализатора: получены одинаковые дисперсности и активности. Углекислые остатки, образующиеся при высоких температурах, удаляют водородом при комнатной температуре, регенерируя, таким образом, активностя.
    Notes: Abstract The activity in n-butane hydrogenolysis of Rh/TiO2 (0.6 wt.% Rh) catalysts prepared by ion exchange and reduced at different heating rates is reported. The heating rate has no major effect on the properties of the catalysts (similar dispersions and activities are achieved). Carbonaceous residues formed at high temperature are removed by hydrogen at room temperature, thus leading to recovery of the activity.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1007/BF02137654
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  • 6
    Electronic Resource
    Electronic Resource
    Hydrogenolysis of n-butane on low-loaded Rh/TiO2. II. Catalysts obtained by impregnation (1992)
    Springer
    Reaction kinetics and catalysis letters 47 (1992), S. 233-238 
    Details
    ISSN: 1588-2837
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology
    Description / Table of Contents: Abstract Описывают активность Rh/TiO2 (0,6 вес. % Rh), приготовленного импрегнированием и qvосстановлением при различных скоростях нагрева, в гидрогенолизе н-бутана. Катализатор, восстановленныи при скорости 5 К/мин, в десять раз активнее катализатора, восстановленного при скорости нагрева 20 К/мин, несмотря на то, что величины дисперсности не отличаются в обоих случаях.
    Notes: Abstract The activity in n-butane hydrogenolysis of Rh/TiO2 (0.6 wt. % Rh) catalysts propared by impregnation and reduced at different heating rates is reported. The catalyst reduced at 5 K/min is ten times more active than that reduced at 20 K/min, despite the fact that the dispersion values are similar in both cases.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1007/BF02137655
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  • 7
    Electronic Resource
    Electronic Resource
    Calcia-supported lanthanide oxides for methane oxidation II. Catalytic properties (1992)
    Springer
    Reaction kinetics and catalysis letters 48 (1992), S. 391-395 
    Details
    ISSN: 1588-2837
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology
    Description / Table of Contents: Abstract Окислы лантана и самария, нанесенные на CaO, приготовленные из нитратов или окислов лантанидов, тестировали в окислении метана. Образцы, приготовленные из окислов, более активны по отношению к полному окислению, а из нитратов — приводят в основном к продуктам C2 и C3.
    Notes: Abstract Lanthanum and samarium oxides supported on CaO, prepared from lanthanide nitrates or oxides, have been tested for methane oxidation. Samples prepared from the oxides are more active for total oxidation. Those from nitrates lead mainly to C2 and C3.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1007/BF02162686
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  • 8
    Electronic Resource
    Electronic Resource
    Li/MgO catalysts. III. Effect of precursor salts on the catalytic activity in methane oxidative coupling (1992)
    Springer
    Reaction kinetics and catalysis letters 48 (1992), S. 455-460 
    Details
    ISSN: 1588-2837
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology
    Description / Table of Contents: Abstract Реакции окислительного соединения метана исследовали на катализаторах Li/MgO, приготовленных из трёх различных предшественников MgO и карбоната или нитрата лития. В образцах, приготовленных из Li2CO3, остатки последнего на поверхности носителя благоприятствуют образованию окислов углерода.
    Notes: Abstract Oxidative coupling of methane has been studied on Li/MgO catalysts prepared from three different MgO precursors and from lithium carbonate or nitrate. In samples prepared from Li2CO3, the persistence of this on the support surface favors formation of carbon oxides.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1007/BF02162694
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  • 9
    Electronic Resource
    Electronic Resource
    An FT-IR spectroscopic assessment of the surface basicity of calcia (1993)
    Springer
    Reaction kinetics and catalysis letters 49 (1993), S. 139-144 
    Details
    ISSN: 1588-2837
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology
    Notes: Abstract Adsorption of formic acid on Ca(OH)2 calcined at increasing temperatures has been monitored by FT-IR spectroscopy. Adsorption takes places dissociatively, forming bidentate formate species, coordinated to surface Ca2+ ions. The basicity decreases as the outgassing temperature increases, due to removal of surface hydroxy groups.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1007/BF02084040
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  • 10
    Electronic Resource
    Electronic Resource
    Hydrogenolysis of light hydrocarbons on Rh/TiO2. Catalysts reduced at low temperature (1986)
    Springer
    Reaction kinetics and catalysis letters 32 (1986), S. 221-226 
    Details
    ISSN: 1588-2837
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology
    Description / Table of Contents: Abstract Гидрогенолиз углеводородов состава C2 до C4 на Rh/TiO2 (2,5 вес. % Rh) исследовали на окисленных и вновь восстановленных катализаторах. После восстановления и окисления при 773 К, восстановление при низких температурах увеличивает активность, которая уменьшается при увеличении температуры ревосстановления. Определены параметры реакции (энергия активации и частотный фактор).
    Notes: Abstract Hydrogenolysis of C2 to C4 hydrocarbons on Rh/TiO2 (2.5 wt. % Rh) has been studied on catalysts oxidized and rereduced. After reduction and oxidation at 773 K, reduction at lower temperatures increases the activity, but this decreases as the re-reduction temperature increases. The reaction parameters (activation energy and frequency factor) have been determined.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1007/BF02063476
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