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  • 1
    ISSN: 1436-5073
    Keywords: decomposition ; mass spectrometry ; ceramics ; fluorine ; isotope ratio
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology
    Notes: Abstract The features of a combustion with elementary fluorine for the case of compact SiC ceramics and model substances for boron containing ceramics (H3BO3 and Na2B4O7) were investigated with the aim of their decomposition and analysis. On-line detection of the gaseous decomposition products by quadrupole mass spectrometry using electron impact ionisation was studied. Limitations by blanks and transport interferences were investigated. Standard addition as well as the isotope dilution technique were used for calibration in the case of B, C and W at the trace and major component level.
    Type of Medium: Electronic Resource
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  • 2
    ISSN: 1436-5073
    Keywords: radiofrequency glow discharge ; mass spectrometry ; energy distribution
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology
    Notes: Abstract The analytical capabilities of a high-resolution mass spectrometer in combination with a 13.56 MHz glow discharge ion source for the analysis of semiconducting materials (silicon carbide and gallium arsenide) were studied. It was shown that single positively charged ions of sample material have about 10 eV higher average energy than the ions of the discharge and residual gas. Therefore effective energy separation of the ions of analyte from the ions of the discharge and residual gas was achieved by adjusting the ion transfer optics (breadth and position of energy slit), which improves the analytical capabilities of the developed method. Some analytical applications are presented to illustrate the performance of r.f. GDMS for the bulk analysis of semiconducting materials. The results of the trace element analysis of gallium arsenide and silicon carbide samples are compared with data of independent methods (LIMS, ICP-AES, SIMS).
    Type of Medium: Electronic Resource
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