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  • 1
    Electronic Resource
    Electronic Resource
    On the Oximine Complexes of Transition Metals 106. Spectroscopic and DSC Study of Some Complexes of the Types [Cu(DioxH)2] and [CuX2·DioxH2] (1998)
    Springer
    Journal of thermal analysis and calorimetry 53 (1998), S. 421-429 
    Details
    ISSN: 1572-8943
    Keywords: copper(II)-oxime complexes ; DSC ; kinetic parameters
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology
    Notes: Abstract Several new complexes of the types [Cu(DioxH)2] and [CuX2·DioxH2] (DioxH2: aliphatic or alicyclic α-dioxime) were obtained and characterized by means of near and far Fourier transformation IR spectroscopy. The thermal decompositions of seven complexes of these types were studied by using DSC measurement data. For several decomposition stages, apparent kinetic parameters were derived by means of the nomogram method.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1023/A:1010129022837
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  • 2
    Electronic Resource
    Electronic Resource
    On the Oximine Complexes of Transition Metals: Part 110: Spectroscopic and DSC study on some [Fe(Diox·H)2L2] and [Fe(Diox)3(BOR)2] type chelates and clathrochelates (1999)
    Springer
    Journal of thermal analysis and calorimetry 57 (1999), S. 433-445 
    Details
    ISSN: 1572-8943
    Keywords: DSC ; iron(II)-oxime complexes ; kinetic parameters ; Mössbauer spectroscopy
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology
    Notes: Abstract A number of 15 [Fe(Diox#x00B7;H)2L2] type chelates and [Fe(Diox)3(BOR)2] clathrochelates (Diox#x00B7;H2 — dimethylglyoxime, glyoxime, propoxime, nyoxime, furyl-dioxime; L-pyridine, alkyl-pyridine derivatives, diethyl-phenyl-phosphine, diethyl-p-tolyl-phosphine) were obtained and characterized by means of far and middle FTIR and Mössbauer spectroscopic methods. Some structural problems were discussed on the basis of the optical data. The DSC measurements show the higher thermal stability of the clathrochelates without O—H⋯O intramolecular hydrogen bonds (with asymmetric octahedral structure), as compared to the [Fe(Diox#x00B7;H)2L2] trans, symmetric chelates containing O—H⋯O bonds. The kinetic parameters of the thermal decomposition of the complexes have been derived using the nomogram method.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1023/A:1010155706218
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  • 3
    Electronic Resource
    Electronic Resource
    Kinetic analysis of thermogravimetric data (1992)
    Springer
    Journal of thermal analysis and calorimetry 38 (1992), S. 2301-2310 
    Details
    ISSN: 1572-8943
    Keywords: hexabromoplatinate complexes ; kinetic parameters ; pyrolysis processes
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology
    Description / Table of Contents: Zusammenfassung Es wurden die Kalium-, Ammonium- und dreizehn verschiedene Aminsalze von Hexabromoplatinsäure hergestellt und mittels Elementaranalyse charakterisiert. Mittels Derivatographie und DSC wurde die thermische Zersetzung dieser Komplexsalze untersucht. Das Wesen der Pyrolysevorgänge wird besprochen und mit dem der analogen Chlorokomplexe verglichen. Anhand der TG-Kurven wurden für verschiedene Schritte der thermischen Zersetzung kinetische Parameter ermittelt.
    Notes: Abstract The potassium, ammonium and thirteen amine salts of hexabromoplatinic acid were obtained and characterized by chemical analysis. The thermal decompositions of these complex salts were studied by derivatograph and differential scanning calorimetry. The natures of the pyrolysis processes are discussed and compared with those obtained for the analogous chlorocomplexes. From the TG curves, kinetic parameters were derived for different stages of the thermal decomposition.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1007/BF02123983
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