ISSN:
1588-2837
Schlagwort(e):
K-promoted Zn/Cr spinel catalysts
;
higher alcohol synthesis
;
isobutanol
;
methanol
;
synthesis gas
Quelle:
Springer Online Journal Archives 1860-2000
Thema:
Chemie und Pharmazie
Notizen:
Abstract Promoter loading level significantly affects the catalytic behavior of Zn/Cr spinel higher alcohol synthesis (HAS) catalysts. In this study a 5.9 wt.% Pd-promoted Zn/Cr spinel with a 5 and 7 wt.% K promoter have been tested and compared. At 1500 psig and 400°C, the catalyst containing 5 wt.% K results in the production of slightly more butanol, less methanol and more hydrocarbons. Using ion scattering spectroscopy and X-ray photoelectron spectroscopy, differences are found between the two catalyst surfaces which must be responsible for the differences in catalytic behavior.
Materialart:
Digitale Medien
URL:
http://dx.doi.org/10.1007/BF02475764
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