ISSN:
1572-882X
Schlagwort(e):
microcrystallite
;
colloid-crystal
;
ultrasound
;
anisotropic phase
;
hydrolysis
Quelle:
Springer Online Journal Archives 1860-2000
Thema:
Land- und Forstwirtschaft, Gartenbau, Fischereiwirtschaft, Hauswirtschaft
,
Werkstoffwissenschaften, Fertigungsverfahren, Fertigung
Notizen:
Abstract Stable colloidal suspensions of cellulose microcrystallites may be prepared from filter paper by sulfuric acid hydrolysis. Above a critical concentration, the suspensions form a chiral nematic ordered phase, or ‘colloid crystal’. The preparation conditions govern the properties of the individual cellulose microcrystallites, and hence the liquid crystalline phase separation of the cellulose suspensions. The particle properties and the phase separation of the suspensions were strongly dependent on the hydrolysis temperature and time, and on the intensity of the ultrasonic irradiation used to disperse the particles. The particle size of the microcrystallites was characterized with transmission electron microscopy and photon correlation spectroscopy. The surface charge was determined by conductometric titration. It was possible to fractionate the microcrystallites by size using the partitioning between isotropic and liquid crystalline phases; the longer microcrystallites migrate to the liquid crystalline phase
Materialart:
Digitale Medien
URL:
http://dx.doi.org/10.1023/A:1009260511939
Permalink
