ISSN:
0894-3230
Schlagwort(e):
reactant-solute encounters
;
aqueous solutions
;
water
;
kinetic methods
;
hydration cosphere destructive overlap
;
camouflage effects
;
Chemistry
;
Theoretical, Physical and Computational Chemistry
Quelle:
Wiley InterScience Backfile Collection 1832-2000
Thema:
Chemie und Pharmazie
,
Physik
Notizen:
Rates of chemical reactions in aqueous solutions are often sensitive to low concentrations of added solutes such as ureas, alcohols, α-amino acids and carbohydrates. In this work, several simple chemical reactions were used to probe this sensitivity, which arises from interactions between added solute and the reacting solute. It was found that derived interaction parameters provide a novel insight into interactions between solute molecules in aqueous solution. For example, it was possible to identify two interesting effects, which are termed (i) ‘destructive overlap’ of hydration cospheres and (ii) ‘camouflage effects’ by water-solute interactions. Copyright © 1998 John Wiley & Sons, Ltd.
Zusätzliches Material:
2 Ill.
Materialart:
Digitale Medien
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