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The influence of substituted alcohols on the temperature of maximum density of water (1976)

Macdonald, Digby D. ; Dolan, B. ; Hyne, J. B.

Springer

Journal of solution chemistry 5 (1976), S. 405-416

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ISSN: 1572-8927

Keywords: Temperature of maximum density of water ; trifluoroethanol ; trichloroethanol ; tribromoethanol ; n-pentyl alcohol ; hexafluoroisopropanol

Source: Springer Online Journal Archives 1860-2000

Topics: Chemistry and Pharmacology

Notes: Abstract The influence of various substituted (including halogenated) alcohols on the temperature of maximum density (TMD) of water has been investigated. Evaluation of the structural contribution to the shift in the TMD demonstrates that trifluoroethanol, hexafluoroisopropanol, and neopentyl alcohol are “structure makers”, whereas trichloroethanol and tribromoethanol are “structure breakers”. The results are discussed in terms of an excluded volume model.

Type of Medium: Electronic Resource

URL: http://dx.doi.org/10.1007/BF00646415

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