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  • delayed feedback information  (1)
  • oxidation  (1)
  • 1
    Electronic Resource
    Electronic Resource
    On the optimal control of arrivals to a single queue with arbitrary feedback delay (1997)
    Springer
    Queueing systems 27 (1997), S. 1-16 
    Details
    ISSN: 1572-9443
    Keywords: Markov decision theory ; delayed feedback information ; threshold policies
    Source: Springer Online Journal Archives 1860-2000
    Topics: Computer Science
    Notes: Abstract We consider a problem of admission control to a single queue in discrete time. The controller has access to k step old queue lengths only, where k can be arbitrary. The problem is motivated, in particular, by recent advances in high-speed networking where information delays have become prominent. We formulate the problem in the framework of Completely Observable Controlled Markov Chains, in terms of a multi-dimensional state variable. Exploiting the structure of the problem, we show that under appropriate conditions, the multi-dimensional Dynamic Programming Equation (DPE) can be reduced to a unidimensional one. We then provide simple computable upper and lower bounds to the optimal value function corresponding to the reduced unidimensional DPE. These upper and lower bounds, along with a certain relationship among the parameters of the problem, enable us to deduce partially the structural features of the optimal policy. Our approach enables us to recover simply, in part, the recent results of Altman and Stidham, who have shown that a multiple-threshold-type policy is optimal for this problem. Further, under the same relationship among the parameters of the problem, we provide easily computable upper bounds to the multiple thresholds and show the existence of simple relationships among these upper bounds. These relationships allow us to gain very useful insights into the nature of the optimal policy. In particular, the insights obtained are of great importance for the problem of actually computing an optimal policy because they reduce the search space enormously.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1023/A:1019145611110
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  • 2
    Electronic Resource
    Electronic Resource
    Effect of sulfuric acid on reactions of peroxymonosulfate ion with sulfides and thiol esters (1998)
    Chichester : Wiley-Blackwell
    Journal of Physical Organic Chemistry 11 (1998), S. 803-808 
    Details
    ISSN: 0894-3230
    Keywords: peroxymonosulfate ion ; oxidation ; sulfuric acid ; Chemistry ; Theoretical, Physical and Computational Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Physics
    Notes: Peroxymonosulfate ion, HSO5-, as Oxone in aqueous H2SO4, oxidizes sulfides [MeSC6H4X(p), X = Me, H, NO2] to sulfoxides and converts aryl thiobenzoates [PhCOSC6H4X(p), X = Me, H] and thiol phosphorus(V) esters [Ph2POSPh, (EtO)2POSPh, Ph2POSEt, Ph(EtO)POSEt] into the acids and sulfonate ions. Second-order rate constants increase with increasing concentration of H2SO4 (10-53 wt%), owing to the high polarity of the medium rather than to acid catalysis. The rate increases fit the Grunwald-Winstein equation based on YOTs solvent parameters derived from rate effects on SN1 solvolyses. © 1998 John Wiley & Sons, Ltd.
    Additional Material: 7 Ill.
    Type of Medium: Electronic Resource
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