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Metal complexes with pyrazole-derived ligands (1996)

Petrović, A. F. ; Lukić, S. R. ; Petrović, D. M. ; [et al.]

Springer

Journal of thermal analysis and calorimetry 47 (1996), S. 879-886

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ISSN: 1572-8943

Keywords: complexes ; cobalt(II) ; 3(5)-amino-4-acetyl-5(3)-methilpyrazole ; thermal decomposition

Source: Springer Online Journal Archives 1860-2000

Topics: Chemistry and Pharmacology

Notes: Abstract The thermal decomposition of tetrahedral cobalt(II) complexes with 3(5)-amino-4-acetyl5(3)-methylpyrazole (HL) of the general formula [Co(HL)2X2] (X=Cl, Br, I, NCO, NCS) and octahedral [Co(HL)2(H2O)4](NO3)2 and [Co(HL)2−N(CN)2}2] complexes was investigated in air atmosphere in the interval from room temperature to 1000°C. Decomposition of the complexes occurred in several successive endothermic and exothermic processes, and the residue was in all cases CoO.

Type of Medium: Electronic Resource

URL: http://dx.doi.org/10.1007/BF01981822

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