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Synthesis, characterization, and reactivity studies of alkylidyne palladium cluster compounds (1996)

Vilar, Ramon ; Michael, D. ; Mingos, P.

Springer

Journal of cluster science 7 (1996), S. 663-675

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ISSN: 1572-8862

Keywords: Palladium ; cluster ; alkylidyne ; catalysis

Source: Springer Online Journal Archives 1860-2000

Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics

Notes: Abstract [Pd4(μ3-CR)(μ-Cl)3(PBu 3 1 )4] (R = H, F) have been synthesized from [Pd2(dba)3]. PBu 3 1 and CRCl3 and characterized spectroscopically and in one case by a single crystal X-ray crystallographic analysis, These compounds undergo substitution reactions with LiBr and tertiary phosphines and are catalyst for the polymerization of ethyne. Details of these reactions are discussed for the compound [ Pd4(μ3-CR)(μ-Cl)3(PBu 3 1 )4]. The cluster lbrmation reactions. have been monitored using31P(1H)NMR studies.

Type of Medium: Electronic Resource

URL: http://dx.doi.org/10.1007/BF01165808

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