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  • 1
    Electronic Resource
    Electronic Resource
    Springer
    Hyperfine interactions 113 (1998), S. 261-267 
    ISSN: 1572-9540
    Keywords: mechanical alloying ; ceramic oxides ; microstructure ; gas sensitivity ; Mössbauer spectroscopy
    Source: Springer Online Journal Archives 1860-2000
    Topics: Physics
    Notes: Abstract Metastable α-Fe2O3-MO2(M: Sn and Ti) solid solutions can be synthesized by mechanical alloying. The alloy formation, microstructure, and gas sensitive properties of mechanically milled α-Fe2O3-SnO2 materials are discussed. Tin ions in α-Fe2O3 are found to occupy the empty octahedral holes in the α-Fe2O3 lattice. This interstitial model can also describe the structure of α-Fe2O3-TiO2solid solutions. Finally, a correlation of gas sensitive properties with microstructure of α-Fe2O3-SnO2 materials is presented.
    Type of Medium: Electronic Resource
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