ISSN:
0268-2605
Keywords:
siloxanes
;
carbohydrate modified
;
surfactants
;
saccharide
;
Chemistry
;
Industrial Chemistry and Chemical Engineering
Source:
Wiley InterScience Backfile Collection 1832-2000
Topics:
Chemistry and Pharmacology
Notes:
New siloxanyl-modified carbohydrate surfactants of the amide and glycoside type have been synthesized by coupling between defined as well as higher-molecular-weight siloxanes and carbohydrate structures via spacers of different lengths and hydrophilic power. Linear and branched monohydrogen di-, tri-, tetra- and penta-siloxanes and polyhydrogen siloxanes as well as mono- and di-saccharide lactone structures have been found to be good starting materials for the synthesis of amides, often in quantitative yield, whereas glycosides had to be prepared in low-yield multistep sequences including protection/deprotection steps. Selected strategies were applied to polysiloxanes yielding quantitatively a broad variety of carbohydrate-modified comb-like structures. The new substances were characterized by means of 13C NMR spectroscopy, GC, capillary GC, GC-MS coupling and elemental analysis.
Additional Material:
3 Ill.
Type of Medium:
Electronic Resource
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