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  • 1
    ISSN: 1573-1561
    Keywords: Cinnamic acids ; bird repellents ; quantitative structure–activity relationship ; dose–response ; pigeon ; Columba livia ; crop protection ; feeding deterrent
    Source: Springer Online Journal Archives 1860-2000
    Topics: Biology , Chemistry and Pharmacology
    Notes: Abstract Plants have evolved an array of defense chemicals that inhibit the feeding of vertebrate herbivores and therefore have potential for agricultural and environmental applications to reduce feeding damage. We investigated the relationship between structure and repellency for 14 derivatives of the plant secondary compound, cinnamic acid, using the feral pigeon (Columba livia) as the test species. The mechanism behind the repellent activity of these derivatives is explained by a combination of four descriptors: heat of formation (ΔH f), polarizability (XY and YY) and superdelocalizability (Sr). All these parameters are electronic, indicating that changes in electronic distribution within cinnamic acid structures are crucial for activity. This is the first published quantitative structure–activity model for avian repellents, and as a result we can now begin to predict which cinnamic acid derivatives should make effective repellents. The full power of this model to aid the selection and screening of new repellents awaits further experimentation on both related compounds and other avian species. However, this modeling approach promises to provide a more efficient and economic method for prospecting chemical databases for new effective bird repellents.
    Type of Medium: Electronic Resource
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  • 2
    Electronic Resource
    Electronic Resource
    Springer
    Agroforestry systems 34 (1996), S. 259-264 
    ISSN: 1572-9680
    Keywords: Acer pseudoplatanus ; damage ; Fraxinus excelsior ; herbivory ; plastic tree-shelters
    Source: Springer Online Journal Archives 1860-2000
    Topics: Agriculture, Forestry, Horticulture, Fishery, Domestic Science, Nutrition
    Notes: Abstract Direct herbivore damage to trees in temperate silvopastoral agroforestry systems is a major management consideration. Individual plastic tree-shelters may sometimes cause poor tree development and they have limited life span. Therefore, some alternative tree-shelter products were tested on four year old Acer pseudoplatanus and Fraxinus excelsior. Damage to the main stem was assessed by determining the area of bark removed by sheep browsing. Wobra®, a paint-on abrasive substance applied to the main stem, was effective in reducing sheep damage. However, some damage did occur due to breach of the protective barrier as a result of stem diameter increases and its removal through rubbing by animals. Anipel®, a systemic bittering agent supplied through the root system, was not effective in preventing significant damage compared to no-treatment controls, possibly because of poor uptake of the active ingredient into the tree. Within treatments, there were significant differences in damage incurred. Most notably Fraxinus suffered more damage than Acer, an effect which may be related to differences in tree size and/or relative palatability.
    Type of Medium: Electronic Resource
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