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  • biogenic emission  (1)
  • nitrogen oxides  (1)
  • ozone deposition to grassland  (1)
  • ozone precursors  (1)
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  • 1
    ISSN: 1573-0662
    Schlagwort(e): Tropospheric ozone ; ozone precursors ; photochemistry ; nitrogen oxides ; rural ozone
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Chemie und Pharmazie , Geologie und Paläontologie
    Notizen: Abstract The seasonal and diurnal variations of ozone mixing ratios have been observed at Niwot Ridge. Colorado. The ozone mixing ratios have been correlated with the NO x (NO+NO2) mixing ratios measured concurrently at the site. The seasonal and diurnal variations in O3 can be reasonably well understood by considering photochemistry and transport. In the winter there is no apparent systematic diurnal variation in the O3 mixing ratio because there is little diurnal change of transport and a slow photochemistry. In the summer, the O3 levels at the site are suppressed at night due to the presence of a nocturnal inversion layer that isolated ozone near the surface, where it is destroyed. Ozone is observed to increase in the summer during the day. The increases in ozone correlate with increasing NO x levels, as well as with the levels of other compounds of anthropogenic origin. We interpret this correlation as in-situ or in-transit photochemical production of ozone from these precursors that are transported to our site. The levels of ozone recorded approach 100 ppbv at NO x mixing ratios of approximately 3 ppbv. Calculations made using a simple clean tropospheric chemical model are consistent with the NO x -related trend observed for the daytime ozone mixing ratio. However, the chemistry, which does not include nonmethane hydrocarbon photochemistry, underestimates the observed O3 production.
    Materialart: Digitale Medien
    Standort Signatur Erwartet Verfügbarkeit
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  • 2
    Digitale Medien
    Digitale Medien
    Springer
    Journal of atmospheric chemistry 4 (1986), S. 429-444 
    ISSN: 1573-0662
    Schlagwort(e): Biosphere-atmosphere exchange ; biogenic emission ; eddy correlation ; dry deposition ; nitrogen oxides fluxes ; ozone deposition to grassland ; turbulent exchange
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Chemie und Pharmazie , Geologie und Paläontologie
    Notizen: Abstract Using the eddy correlation method, fluxes of nitric oxide, nitrogen dioxide, ozone, water, and sensible heat were measured at a site 20 km north of Denver, Colorado over mature crested wheat grass, 0.75 m high in late June and early July. During this period the weather was fair with no synoptic disturbances. In the early morning a well-mixed diluted urban pollution plume traversed the site, by late morning aged pollution had mixed downward into the local boundary layer, and by afternoon the air came from a relatively unpolluted area of the high plains. The mean trace gas concentrations reflect this repeated pattern of local air flow. The fluxes of the trace gases were influenced both by the variation of the means and by other factors including temperature and biological activity. Ozone fluxes were found to be always negative and proportional to the mean, with an average deposition velocity for this case of about 0.006 m s-1. For the oxides of nitrogen this simple treatment was not appropriate. Both deposition and emission were observed, generally deposition predominated in the morning and emission in the afternoon with observed variations in the fluxes of NOx=NO+NO2 from −0.3 to +0.2 ppbv m s-1.
    Materialart: Digitale Medien
    Standort Signatur Erwartet Verfügbarkeit
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