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  • 1
    Electronic Resource
    Electronic Resource
    Springer
    International journal of thermophysics 10 (1989), S. 713-726 
    ISSN: 1572-9567
    Keywords: fluorinol ; kinematic viscosity ; mixing rules ; mixtures ; pure fluids ; trifluoroethanol ; water
    Source: Springer Online Journal Archives 1860-2000
    Topics: Physics
    Notes: Abstract The kinematic viscosity of pure 2,2,2-trifluoroethanol, water, and their mixtures was measured with Ubbelohde capillary viscometers at ambient pressure. The study covers the full range of compositions in the liquid region between the bubble and the freezing line. The viscosity was found to vary by a factor of 280 from 0.30 to 87.2 cSt. It exhibits a pronounced maximum at high H2O mole fractions and a flat minimum at high TFE concentrations. The temperature dependence of viscosity was correlated individually for each composition and three mixing rules were tested which are widely used for alcohol-water mixtures. The data were represented best with Dizechi's equation.
    Type of Medium: Electronic Resource
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  • 2
    ISSN: 1572-9567
    Keywords: ammonia ; alternative refrigerants ; capillary viscometer ; R32 ; R134a ; saturated liquid ; radial acceleration correction ; vapor buoyancy ; viscosity
    Source: Springer Online Journal Archives 1860-2000
    Topics: Physics
    Notes: Abstract The saturated liquid viscosity of ammonia (NH3) and of the hydrofluorocarbons, difluoromethane (CH2F2, R32) and 1,1,1,2-tetrafluoroethane (CF3–CH2F, R134a), was measured in a sealed gravitational viscometer with a straight vertical capillary. The combined temperature range was from 250 to 350 K. The estimated uncertainty of the ammonia measurements is ±3.3 and ±2 to 2.4% for the hydrofluorocarbons with a coverage factor of two. The results are compared with literature data which have been measured with capillary viscometers of different design. Agreement within the combined experimental uncertainty is achieved when some of the literature data sets are corrected for the vapor buoyancy effect and when a revised radial acceleration correction is applied to data which were obtained in viscometers with coiled capillaries. An improved correction for the radial acceleration is proposed. It is necessary to extend inter-national viscometry standards to sealed gravitational capillary instruments because the apparent inconsistencies between refrigerant viscosity data from different laboratories cannot be explained by contaminated samples.
    Type of Medium: Electronic Resource
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