ISSN:
0887-624X
Keywords:
terpolymerization
;
charge transfer complex
;
allylglycidyl ether
;
maleic anhydride
;
methyl methacrylate
;
thermo-crosslinking
;
photo-crosslinking
;
thermal degradation
;
Chemistry
;
Polymer and Materials Science
Source:
Wiley InterScience Backfile Collection 1832-2000
Topics:
Chemistry and Pharmacology
Notes:
Radical copolymerization of donor-acceptor monomers, i.e., allylglycidyl ether (AGE), maleic anhydride (MA) and methyl methacrylate (MMA) are studied, where binary copolymerization of AGE...MA complex with MMA is obtained. Constants of charge transfer complex formation (Kc) and copolymerization (r1 and r2) are determined by 1H-NMR and Kelen-Tüdöş methods, respectively. It is found that synthesized film-forming terpolymers with free epoxy and anhydride groups on side chain of macro-molecules are being crosslinked easily under the effect of temperature and/or UV-ir-radiation. Observed crosslinking effect is proved by the DTA, TGA, and IR spectroscopic analyses. It is shown that complex-radical terpolymerization is very convenient method for the designing of reactive functional macromolecules of linear structure with self-crosslinking properties which can serve as a basis for the use in photolithographic applications. © 1995 John Wiley & Sons, Inc.
Additional Material:
8 Ill.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1002/pola.1995.080330905
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