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  • 1
    Electronic Resource
    Electronic Resource
    Hydration of alcohols in aqueous methanol solutions from ultrasonic velocity measurements (1983)
    Springer
    Journal of solution chemistry 12 (1983), S. 783-789 
    Details
    ISSN: 1572-8927
    Keywords: Ultrasonic velocity ; aqueous methanolic solutions ; alcohols ; hydration
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology
    Notes: Abstract Ultrasonic velocity maxima, as a function of alcohol concentration in aqueous methanol solution, have been determined for solutions of a number of mono- and polyhydroxyalcohols. The location of the maximum relative to that in the water-methanol system alone was related to the hydration of the solute molecule. Calculated hydration numbers are linearly correlated with the number of hydroxyl groups in the case of polyhydroxyalcohols, and with the surface area of the non-polar regions in the case of monohydroxyalcohols.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1007/BF00653181
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  • 2
    Electronic Resource
    Electronic Resource
    Hydration of alcohols by ultrasonic velocity measurements in ternary systems (1984)
    Springer
    Journal of solution chemistry 13 (1984), S. 493-503 
    Details
    ISSN: 1572-8927
    Keywords: Ultrasonic velocity ; ternary aqueous systems ; alcohols ; hydration
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology
    Notes: Abstract Ultrasonic velocity maxima have been determined as a function of alcohol (methanol, ethanol, n-propanol or t-butanol) concentration in ternary aqueous alcoholic solutions of a number of mono- and polyhydroxyalcohols. The location of the maxima relative to those in the binary water-alcohol systems are related to the hydration of the solute molecule. It is established that correlations between the extent of hydration and some structural parameters of the solute molecules are of the same character in all binary solvents studied.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1007/BF00647174
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    Paper (German National Licenses)
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