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  • UV grafting  (1)
  • polystyrene  (1)
  • 1
    Digitale Medien
    Digitale Medien
    Springer
    Plasma chemistry and plasma processing 9 (1989), S. 3-12 
    ISSN: 1572-8986
    Schlagwort(e): Etching ; polystyrene ; polymethylmethacrylate ; ion bombardment
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Chemie und Pharmazie , Maschinenbau , Technik allgemein
    Notizen: Abstract The effect of low-energy ion bombardment on CD4/O2 and CF3X (X=F, Cl, Br) plasma etching has been assessed by applying controlled rf bias voltages on polystyrene (PS) and polymethylmethacrylate (PMMA) samples. In both cases ion bombardment has been found to have a “chemical” effect. In the case of CF4/O2 discharges, ion bombardment has been found to change the relative etching efficiency of different mixtures. In the case of CF3X plasmas, ion bombardment has been found to alter PMMA and PS etch rates in a different way. In particular, the ratios between CF4 and CF3X (X=Cl, Br) etch rates of PS have been found to decrease with increasing bias voltage. This effect has been tentatively attributed to an ion bombardment-induced enhancement of the reaction between the aromatic ring and halogen molecules formed in CF3Cl and CF3Br discharges.
    Materialart: Digitale Medien
    Standort Signatur Erwartet Verfügbarkeit
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  • 2
    Digitale Medien
    Digitale Medien
    Springer
    Colloid & polymer science 271 (1993), S. 696-704 
    ISSN: 1435-1536
    Schlagwort(e): Wettability ; dynamic contact angle ; UV grafting ; hydrophilic surfaces
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Chemie und Pharmazie , Maschinenbau
    Notizen: Abstract The wetting behavior of vapor phase photografted hydrophilic acrylic monomers was evaluated by the three most commonly employed techniques, i.e., the captive bubble, the sessile drop, and the Wilhelmy plate technique. The measured contact angles and the overall wetting behavior were discussed in light of the non-ideal nature of these surfaces. It was found that the peculiar nature of hydrophilic grafted surfaces is carefully reflected in the experimentally measurable contact angles. While in the case of the captive bubble the hydrophilic and rough nature of these coatings prevent the bubble-surface contact, in the case of the sessile drop the measured contact angles follow the behavior predicted by contact angle hysteresis theories. Wilhelmy plate measurements, performed as sequential scanning loops, show velocity-dependent effects which are linked to the composition, morphology and mobility of the grafted surfaces.
    Materialart: Digitale Medien
    Standort Signatur Erwartet Verfügbarkeit
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