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Photochemical Synthesis and Reactivity of New Chloro-Bridged Complexes with Tungstenocene (η5-C5H5)(η5-C5H4PPh2)WClX (X = H, Cl) and Tetracarbonylmetal (Cr, W) Units (1999)

Comte, Virginie ; Kubicki, Marek M. ; Moïse, Claude

Weinheim : Wiley-Blackwell

Berichte der deutschen chemischen Gesellschaft 1999 (1999), S. 2029-2035

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ISSN: 1434-1948

Keywords: Tungsten ; Sandwich complexes ; Bimetallic compounds ; Carbonyl complexes ; Chemistry ; General Chemistry

Source: Wiley InterScience Backfile Collection 1832-2000

Topics: Chemistry and Pharmacology

Notes: Chloro-bridged bimetallic complexes (η5-C5H5)[η5-C5H4PPh2M′(CO)4]W(μ-Cl)X [X = Cl (3), × = H (4); M′ = Cr, W] were prepared by photochemical irradiation of (η5-C5H5)[η5-C5H4PPh2M′(CO)5]WClX [X = Cl (1), × = H (2); M′ = Cr, W]. The reactivity of the chloro-bridged complexes towards Lewis bases was studied; by exposure to CO or phosphanes, a facile cleavage of the chloro bridge accompanied by regio- and stereospecific coordination at M′ occurs. The X-ray structure of complex 3 (M′ = W) is reported.

Additional Material: 1 Ill.

Type of Medium: Electronic Resource

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