ISSN:
0749-1581
Keywords:
EPR
;
ESR
;
ENDOR
;
TRIPLE RESONANCE
;
INDO
;
Additivity relationship
;
Liquid phase
;
1,4-Benzoquinone
;
1,4-Hydroquinone
;
Methoxybenzoquinone
;
Dimethoxybenzoquinone
;
Trimethoxybenzoquinone
;
Radical reaction
;
Chemistry
;
Analytical Chemistry and Spectroscopy
Source:
Wiley InterScience Backfile Collection 1832-2000
Topics:
Chemistry and Pharmacology
Notes:
The relative signs and absolute values of the hyperfine coupling constants of different methoxy-1,4-benzoquinones were measured by ESR, ENDOR and TRIPLE resonance spectroscopy. Reactions of 1,4-benzoquinone and 1,4-hydroquinone with methanol took place in alkaline methanol, giving rise to methoxy-substituted 1,4-benzoquinones. The same substitution reaction occurred in a mixture of ammonia and methanol. The reactions depended on temperature and the alkali concentration. Coupling constants were assigned by the modified additivity relationship method. An extremely small line width of 0.014 G was measured in the ESR spectrum of deuterated 2,5-dimethoxy-1,4-benzoquinone.
Additional Material:
6 Ill.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1002/mrc.1260280313
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